4-nonafluorobutylstyrene | 159241-92-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-nonafluorobutylstyrene
• 英文别名: 4-(Nonafluorobutyl)styrene；1-ethenyl-4-(1,1,2,2,3,3,4,4,4-nonafluorobutyl)benzene
• CAS: 159241-92-6
• 化学式: C₁₂H₇F₉
• 分子量: 322.173
• InChiKey: ZGUIRKVONJNPDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  4-nonafluorobutylstyrene 在 dihydrogen hexachloroplatinate 三氯硅烷 作用下， 以 甲醇 为溶剂， 生成 Trichloro-[1-(4-nonafluorobutyl-phenyl)-ethyl]-silane 、 Trichloro-[2-(4-nonafluorobutyl-phenyl)-ethyl]-silane
  参考文献：
  名称：

  Synthesis of a silane coupling agent containing a 4-(perfluoroalkyl)phenyl group and its application to the surface modification of glass

  摘要：

  Eight silane coupling agents, CF3(C6H4)C2H4Si(CH3)(OCH3)(2) (C6H4=p-phenylene) (1), C4F9(C6H4)C2H4Si(CH3)(OCH3)(2) (2), C6F13(C6H4)C2H4Si(CH3)(OCH3)(2) (3), C8F17(C6H4)C2H4Si(CH3)(OCH3)(2) (4), CF3(C6H4)C2H4Si(OCH3)(3) (5), C4F9(C4H4)C2H4Si-(OCH3)(3) (6), C6F13(C6H4)C2H4Si(OCH3)(3) (7) and C8F17(C6H4)C2H4Si(OCH3)(3) (8) have been prepared by the hydrosilylation reaction of dichloro(methyl)silane or trichlorosilane with the corresponding 4-perfluoroalkylstyrene in the presence of hydrogen hexachloroplatinate(IV), followed by reaction with sodium methoxide. These new coupling agents were freely soluble in hydrocarbon solvents. Their application for the surface modification of glass has been attempted. From measurements of the contact angles theta (degrees) of water and oleic acid on a modified glass plate surface, it was found that the silane coupling agents show a high degree of surface modification. The oxidation resistance of the modified glass surface has also been investigated.

  DOI：

  10.1016/0022-1139(94)03165-v
• 作为产物：
  描述：

  1-(4'-nonafluorobutylphenyl)ethanol 在 potassium hydrogensulfate 作用下， 以 甲苯 为溶剂， 反应 48.0h， 以77%的产率得到4-nonafluorobutylstyrene
  参考文献：
  名称：

  4'-九氟丁基苯乙烯的常规自由基聚合和碘转移聚合：所得聚（氟苯乙烯）s的表面和热特性

  摘要：

  通过常规和受控的自由基聚合（碘转移聚合（ITP））合成并聚合了4'-Nonafluorobutyl苯乙烯（3）。此类芳族含氟单体是由1-碘全氟丁烷和4-溴苯乙酮之间的Ullmann偶联制得的，然后进行还原和脱水，总收率为50％。（3）的两个自由基聚合反应是由AIBN在常规或受控条件下引发的，其中1-碘全氟己烷的单体转化率为84％，产率为50％。（3）的ITP具有快速单体转化和ln（[M] 0 / [M]）与时间的线性关系。（3）的自由基均聚动力学使人们能够评估其传播速率与终止速率（k p 2 / k t）是根据Tobolsky动力学定律在ITP条件下（80°C下为36.2·10 -2 l·mol -2 ·sec -2）。通过常规聚合获得的含氟聚合物的多分散指数（η）为1.30，而通过ITP合成时则为1.15。这些低聚物的热稳定性令人满意（从305°C到空气中失重10％），而熔点为47°C。从通过常规（磁滞=

  DOI：

  10.1002/pola.26712

文献信息

• COMPOSITION, MODIFICATION METHOD AND SELECTIVE MODIFICATION METHOD OF BASE MATERIAL SURFACE, PATTERN-FORMING METHOD, AND POLYMER
  申请人：JSR CORPORATION

  公开号：US20190194365A1

  公开（公告）日：2019-06-27

  A composition includes a first polymer and a solvent. The first polymer includes a first structural unit including a fluorine atom, and a group including a first functional group at an end of a main chain or a side chain of the first polymer. The first functional group is capable of forming a bond with a metal or a metalloid. The first structural unit preferably includes a fluorinated hydrocarbon group. The first structural unit is preferably derived from a (meth)acrylic ester containing a fluorine atom, or a styrene compound containing a fluorine atom. The first structural unit preferably contains 6 or more fluorine atoms.