[Ag(NCO)(bis(diphenylarsino)ethane)] | 844467-14-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag(NCO)(bis(diphenylarsino)ethane)]
• 英文别名: [Ag(NCO)(dpae)]
• CAS: 844467-14-7
• 化学式: Ag*CNO*C₂₆H₂₄As₂
• 分子量: 636.205
• InChiKey: XVSDQGOEXMFAAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.49
• 重原子数：
  32.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  39.37
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  乙烯二(二苯基胂) 、 silver cyanate 以 乙腈 为溶剂， 以84%的产率得到[Ag(NCO)(bis(diphenylarsino)ethane)]
  参考文献：
  名称：

  New oligo-/poly-meric forms for MX:dpex (1:1) complexes (M=CuI, AgI; X=(pseudo-)halide; dpex=Ph2E(CH2)xEPh2, E=(P), As; x=1, 2)

  摘要：

  Single-crystal X-ray structural characterizations of MX:dpam (1:1) ('dpam' = Ph2AsCH2AsPh2) are reported for MX = AgCl, Br; CuI, CN/Cl (all isomorphous) and AgI, AgSCN, CuSCN arrays, all being of the novel form [(mu-X){M(mu-X)(As-dpam-As')(2)M'}](infinity), essentially the familiar M(E-dpem-E')(2)M' binuclear array with both 'bridging' and (linking) 'terminal' (pseudo-)halides involved in the polymer. A different arrangement of bridging and linking entities is found with AgX:dpae (1:1)(2(infinity\infinity)), X = Br, NCO, 'dpae' = Ph2As(CH2)(2)AsPh2, now comprising [M(mu-X)(2)(As-dpae-As)M] kernels linked by As-dpae-As', while in the thiocyanate analogue Ag((SCN)(NCS))Ag units are linked by the dpae ligands into a two-dimensional web. Synthetic procedures for all adducts have been reported. All compounds have been characterized both in solution (H-1, C-13, P-31 NMR, ESI MS) and in the solid state (IR). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.026