3-[(2-Benzoylhydrazinyl)-phenylmethylidene]-1,1-diethylthiourea | 1206480-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[(2-Benzoylhydrazinyl)-phenylmethylidene]-1,1-diethylthiourea
• CAS: 1206480-84-3
• 化学式: C₁₉H₂₂N₄OS
• 分子量: 354.476
• InChiKey: PFOGEXLKHYLTLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  88.8
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetra-n-butylammonium tetrachlorooxorhenate(V) 、 3-[(2-Benzoylhydrazinyl)-phenylmethylidene]-1,1-diethylthiourea 以 甲醇 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  Rhenium and technetium complexes with tridentate S,N,O ligands derived from benzoylhydrazine

  摘要：

  A potentially tridentate ligand with an S,N,O donor set, H2L, is formed by the reaction of N-[(diethylaminothiocarbonyl)benzimidoyl chloride with benzoylhydrazine. Reactions of H2L with (NBu4)[MOCl4] complexes (M = Re, Tc) give five-coordinate, neutral oxo complexes of the composition [MOCl(L)].Mixed-ligand complexes of rhenium(V) containing the tridentate L2- ligand and bidentate N,N-dialkyl-N'-benzoylthioureato ligands (R(2)btu(-)) are formed in high yields when (NBu4)[ReOCl4] is treated with mixtures of H2L and HR(2)btu. Another approach to the mixed-ligand products is the reaction of [ReOCl(L)] with an equivalent amount of HR(2)btu. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.09.012