4-[(4-甲基苄基)氨基]苯甲酸 | 64518-48-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[(4-甲基苄基)氨基]苯甲酸
• 英文名称: 4-(((4-methylphenyl)methyl)amino)benzoic acid
• 英文别名: 4-[(4-Methylbenzyl)amino]benzoic acid；4-[(4-methylphenyl)methylamino]benzoic acid
• CAS: 64518-48-5
• 化学式: C₁₅H₁₅NO₂
• mdl: MFCD03450495
• 分子量: 241.29
• InChiKey: PSQNWDZFOPXXAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.133
• 拓扑面积：
  49.3
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 海关编码：
  2922499990

反应信息

• 作为产物：
  描述：

  对甲基苯甲醛 、 对氨基苯甲酸 生成 4-[(4-甲基苄基)氨基]苯甲酸
  参考文献：
  名称：

  DE2701854

  摘要：

  公开号：

文献信息

• A binuclear Cu(<scp>ii</scp>) complex as an efficient photocatalyst for <i>N</i>-alkylation of aromatic amines
  作者：Rishi Ranjan、Argha Chakraborty、Reena Kyarikwal、Rakesh Ganguly、Suman Mukhopadhyay

  DOI：10.1039/d2dt01771g

  日期：——

  Visible-light driven photoreactions using transition metal complexes as catalysts are currently a research hotspot in developing environmentally friendly sustainable processes. To develop a potential copper-based photocatalyst, a binuclear Cu(II) complex has been synthesized using a Mannich base ligand viz. 2,4-dichloro-6-((4-(2-hydroxyethyl)piperazin-1-yl)methyl)phenol (H2L). The photocatalyst has

  使用过渡金属配合物作为催化剂的可见光驱动光反应目前是开发环保可持续工艺的研究热点。为了开发一种潜在的铜基光催化剂，使用曼尼希碱配体即合成了双核 Cu( II ) 配合物。2,4-二氯-6-((4-(2-羟乙基)哌嗪-1-基)甲基)苯酚( H 2 L )。已使用 ESI-MS 和单晶 X 射线衍射对光催化剂进行了表征。在可见光照射下，该催化剂可催化氢在N中的自转移-烷基化胺形成和苯甲醇氧化反应，转化率极好。通过 ESI-MS 光谱、UV-Vis 光谱和计算研究探索了催化反应的合理机制途径。
• METHODS OF PRODUCING SUGARS FROM BIOMASS FEEDSTOCKS
  申请人：MIDORI RENEWABLES, INC.

  公开号：US20140060522A1

  公开（公告）日：2014-03-06

  Provided herein are catalysts useful in non-enzymatic saccharification processes. The catalysts can be polymeric catalysts or solid-supported catalysts with acidic and ionic moieties. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using the catalysts described herein.
• POLYMERIC AND SOLID-SUPPORTED CATALYSTS, AND METHODS OF DIGESTING CELLULOSIC MATERIALS USING SUCH CATALYSTS
  申请人：Midori Renewables, Inc.

  公开号：US20150202607A1

  公开（公告）日：2015-07-23

  Provided herein are catalysts useful in non-enzymatic saccharification processes. The catalysts can be polymeric catalysts or solid-supported catalysts with acidic and ionic moieties. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using the catalysts described herein.
• OLIGOSACCHARIDE COMPOSITIONS AND METHODS FOR PRODUCING THEREOF
  申请人：Midori USA, Inc.

  公开号：US20160007642A1

  公开（公告）日：2016-01-14

  Described herein are methods for the production of oligosaccharides, including functionalized oligosaccharides, from one or more sugars, such as one or more monosaccharides, using polymeric and solid-supported catalysts containing acidic and ionic groups. Also provided are the oligosaccharide compositions, including functionalized oligosaccharide compositions, obtained using the methods.
• OLIGOSACCHARIDE COMPOSITIONS FOR USE AS ANIMAL FEED AND METHODS OF PRODUCING THEREOF
  申请人：Midori USA, Inc.

  公开号：US20160366909A1

  公开（公告）日：2016-12-22

  Described herein are methods of producing animal feed made up of oligosaccharide compositions, as well as methods of producing such oligosaccharide compositions and animal feed compositions, and methods of using such animal feed compositions to enhance animal growth.