(1,1,1,5,5,5-hexafluoroacetylacetonato)(1,5-p-tolyl-3-nitroformazanato)palladium(II) | 1064681-34-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1,1,1,5,5,5-hexafluoroacetylacetonato)(1,5-p-tolyl-3-nitroformazanato)palladium(II)
• CAS: 1064681-34-0
• 化学式: C₂₀H₁₅F₆N₅O₄Pd
• 分子量: 609.781
• InChiKey: ZIXKINPFSKWFJR-SHVQJCQISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  palladium(II) hexafluoroacetylacetonate 、 3-nitro-1,5-dip-tolylformazan 以 甲醇 为溶剂， 以47.2%的产率得到(1,1,1,5,5,5-hexafluoroacetylacetonato)(1,5-p-tolyl-3-nitroformazanato)palladium(II)
  参考文献：
  名称：

  Synthesis and characterization of palladium complexes of 3-nitroformazans

  摘要：

  3-Nitroformazans react with bis(1,1,1,5,5,5-hexafluroacetylacetonato) palladium to afford monometallic complexes. The complexes were characterized via X-ray crystallography, cyclic voltammetry, and electronic spectroscopy. The nature of the aryl substituents on the formazan ligands had a profound effect on the structure and spectroscopy of the complexes, with o-substituted aromatic rings twisted with respect to the ligand, while the p-tolyl substituted derivative adopted a planar structure. The complexes undergo irreversible reductions near -1 V versus Fc/Fc(+). (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.005