| 433937-47-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 433937-47-4
• 化学式: CH₄O*C₂₄H₁₈CoN₄O₆*ClO₄
• 分子量: 648.916
• InChiKey: WSNQCQBPZKUIHD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 二(2-吡啶基)乙二酮 、 水 、 cobalt(II) perchlorate hexahydrate 以 甲醇 、 水 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Metal assisted rearrangement of 2,2′-pyridil with M(ClO4)2·6H2O (M=CoII, NiII and CuII): syntheses, characterization and crystal structures

  摘要：

  With the aim of examining the metal-assisted rearrangement behaviors of 2,2'-pyridil (L), its reactions with M(ClO4)(2)(.)6H(2)O (M = Co-II, Ni-II and Cu-II) were considered. X-ray diffraction analyses of the products reveal the formation of complexes containing 2,2'-pyridilate anion (L-1) or picolinate anion (L-2) as arrangement products of 2,2'-pyridil, induced by different metal ions. [Co-III(L-1)(2)](ClO4)(CH3OH)-C-. (1) and [Ni-II(L-1)(2)](.)2H(2)O (2) have similar mononuclear structures, and it should be noted that the Co-II ion is unstable to oxidation in this process. However, [Cu-II(L-2)(2)](.)2H(2)O (3) forms a one-dimensional linear complex via Cu-O weak interactions. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(01)00913-9