trans-[bis(4'-(4,7,10-trioxadec-1-yn-10-yl)-2,2':6',2''-terpyridine)bis(triethylphosphine)platinum(II)] | 1001868-89-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-[bis(4'-(4,7,10-trioxadec-1-yn-10-yl)-2,2':6',2''-terpyridine)bis(triethylphosphine)platinum(II)]
• CAS: 1001868-89-8
• 化学式: C₅₆H₇₀N₆O₆P₂Pt
• 分子量: 1180.24
• InChiKey: VHSJPYKPRATPBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 iron(II) chloride tetrahydrate 、 trans-[bis(4'-(4,7,10-trioxadec-1-yn-10-yl)-2,2':6',2''-terpyridine)bis(triethylphosphine)platinum(II)] 以 甲醇 为溶剂， 生成 bis(4'-(6-hydroxy-1,4-dioxahexyl)-2,2':6',2''-terpyridine)iron(II) hexafluorophosphate 、 bis(4'-(4,7,10-trioxadec-1-yn-10-yl)-2,2':6',2''-terpyridine)bis(triethylphosphine)platinum(II)iron(II) hexafluorophosphate
  参考文献：
  名称：

  Selective addressing of heteroditopic ligands by iron(II) and platinum(II)

  摘要：

  The heteroditopic ligand 4'-(4,7,10-trioxadec-1-yn-10-yl)- 2,2':6',2 ''-terpyridine, 2, contains an N, N', N ''-donor metal-binding domain that recognizes iron(II), and a terminal alkyne site that selectively couples to platinum( II). This selectivity has been used to investigate routes to the formation of heterometallic systems. The single crystal structures of ligand 2 and the complex [Fe(2)(2)][PF6](2) are reported. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.007
• 作为产物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 4'-(4,7,10-trioxadec-1-yn-10-yl)-2,2':6',2''-terpyridine 在 copper(l) iodide 作用下， 以 二氯甲烷 、 三乙胺 为溶剂， 以35.9%的产率得到trans-[bis(4'-(4,7,10-trioxadec-1-yn-10-yl)-2,2':6',2''-terpyridine)bis(triethylphosphine)platinum(II)]
  参考文献：
  名称：

  Selective addressing of heteroditopic ligands by iron(II) and platinum(II)

  摘要：

  The heteroditopic ligand 4'-(4,7,10-trioxadec-1-yn-10-yl)- 2,2':6',2 ''-terpyridine, 2, contains an N, N', N ''-donor metal-binding domain that recognizes iron(II), and a terminal alkyne site that selectively couples to platinum( II). This selectivity has been used to investigate routes to the formation of heterometallic systems. The single crystal structures of ligand 2 and the complex [Fe(2)(2)][PF6](2) are reported. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.007