phenyl-phosphonous acid di-o-tolyl ester | 102315-90-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl-phosphonous acid di-o-tolyl ester
• 英文别名: Phenyl-bis-o-tolyloxy-phosphin；Phenyl-phosphonigsaeure-di-o-tolylester；Bis(2-methylphenoxy)-phenylphosphane
• CAS: 102315-90-2
• 化学式: C₂₀H₁₉O₂P
• 分子量: 322.343
• InChiKey: UKMLQBYODLENBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  邻甲酚 、 苯基二氯化磷 生成 phenyl-phosphonous acid di-o-tolyl ester
  参考文献：
  名称：

  Arbusow et al., Metodiceskij sbornik, 1951, # 16, p. 17,19

  摘要：

  DOI：

文献信息

• [EN] PROCESS FOR THE PREPARATION OF AN (HETERO)ARYLAMINE<br/>[FR] PROCEDE DE PREPARATION D'UNE (HETERO)ARYLAMINE
  申请人：DSM IP ASSETS BV

  公开号：WO2006009431A1

  公开（公告）日：2006-01-26

  The present invention relates to a process for the preparation of an (hetero)arylamine, wherein an optionally substituted (hetero)aromatic bromide compound is contacted with a nucleophilic organic nitrogen-containing compound in the presence of a base, and a catalyst comprising a copper atom or ion and at least one ligand, said ligand comprising at least one coordinating oxygen atom, and if said oxygen atom is part of an OH group, then said OH group is attached to an aliphatic spa carbon atom or to a vinylic carbon atom.

  本发明涉及一种用于制备（杂）芳胺的方法，其中选择性取代的（杂）芳基溴化合物与含有亲核有机氮基团的化合物在碱的存在下接触，并且使用包含铜原子或离子和至少一种配体的催化剂，所述配体包含至少一个配位氧原子，如果所述氧原子是羟基的一部分，则所述羟基连接到一个脂肪烷基碳原子或乙烯基碳原子。
• Process for the Preparation of an (Hetero) Arylamine
  申请人：Lambers Mathilda Maria Henrica

  公开号：US20090012300A1

  公开（公告）日：2009-01-08

  The present invention relates to a process for the preparation of an (hetero)arylamine, wherein an optionally substituted (hetero)aromatic bromide compound is contacted with a nucleophilic organic nitrogen-containing compound in the presence of a base, and a catalyst comprising a copper atom or ion and at least one ligand, said ligand comprising at least one coordinating oxygen atom, and if said oxygen atom is part of an OH group, then said OH group is attached to an aliphatic spa carbon atom or to a vinylic carbon atom.

  本发明涉及一种制备(hetero)arylamine的方法，其中将可选取代的(hetero)芳香溴化合物与含有亲核有机氮化合物在碱的存在下接触，并在催化剂的存在下进行，所述催化剂包括铜原子或离子和至少一个配体，所述配体包括至少一个配位氧原子，如果所述氧原子是OH基团的一部分，则所述OH基团附着在一个脂肪族碳原子或乙烯基碳原子上。
• phosphororganische Antioxidantien. XII. Synthesen und NMR-Spektren phosphororganischer Antioxidantien und verwandter Verbindungen
  作者：T. K�nig、W. D. Habicher、U. H�hner、J. Pionteck、C. R�ger、K. Schwetlick

  DOI：10.1002/prac.19923340407

  日期：——

  The syntheses of various aliphatic, aromatic, sterically hindered, and cyclic organophosphorus compounds (phosphorous acid esters, ester chlorides and ester amides, hydrogen phosphites, phosphonates and phosphates) are reported, and general procedures for preparation are given.The compounds synthesized were investigated by means of P-31-, H-1- and C-13-n.m.r. spectroscopy, and the chemical shifts measured are listed.
• PROCESS FOR THE PREPARATION OF AN (HETERO) ARYLAMINE
  申请人：DSM IP Assets B.V.

  公开号：EP1768947A1

  公开（公告）日：2007-04-04