4-[2,5-二己基-4-(4-羟基苯基)苯基]苯酚 | 141767-98-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[2,5-二己基-4-(4-羟基苯基)苯基]苯酚
• 英文名称: 2',5'-Di-n-hexyl-p-terphenyl-4,4''-diol
• 英文别名: 4-[2,5-Dihexyl-4-(4-hydroxyphenyl)phenyl]phenol
• CAS: 141767-98-8
• 化学式: C₃₀H₃₈O₂
• 分子量: 430.631
• InChiKey: ZAHHBAXJGQKJAW-UHFFFAOYSA-N

物化性质

• 沸点：
  590.3±50.0 °C(Predicted)
• 密度：
  1.038±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  32
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,5-双(己基)-1,4-二溴苯 在 四(三苯基膦)钯 吡啶盐酸盐 、 sodium carbonate 作用下， 以 甲苯 为溶剂， 反应 20.0h， 生成 4-[2,5-二己基-4-(4-羟基苯基)苯基]苯酚
  参考文献：
  名称：

  Synthesis and Properties of Stiff-Chain Polyesters Based on the Terphenyl Moiety

  摘要：

  The synthesis and the characterization of rigid-rod polyesters 2 and 3 deriving from 2',5'-dihexyl-p-terphenyl-4,4''-diol 7 and from 2',5'-dihexyl-p-terphenyl-4,4''-dicarboxylic dichloride 8 together with a facile synthesis of monomers 7 and 8 is described. It is shown that these polyesters exhibit a very good solubility in common organic solvents. Therefore these materials present interesting model compounds for comprehensive studies of rigid-rod polymers in solution.

  DOI：

  10.1080/10587259408037772

文献信息

• A membrane and method for the separation of aromatic hydrocarbons from a mixture of various aromatic hydrocarbons or from a mixture of such aromatic hydrocarbons and non-aromatic hydrocarbons
  申请人：NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO

  公开号：EP0760251A1

  公开（公告）日：1997-03-05

  The invention relates to membranes and to a method for the separation of aromatic hydrocarbons from a mixture of various aromatic hydrocarbons or from a mixture of such aromatic hydrocarbons and non-aromatic hydrocarbons. According to the invention the membrane is formed from aromatic polyesters on the basis of aromatic diacid chlorides in combination with either bisphenol-A-like bisphenols, or a bisphenol which is completely built up of aromatic centres. Preferably the membrane is formed from aromatic polyesters on the basis of aromatic diacid chlorides such as terephthaloyl chloride, isophthaloyl chloride, 5-t-butylisophthaloyl chloride, or PIDA in combination with bisphenol-A-like bisphenols, such as 4X-BPN, 4X-BPT, 4X-BPI.

  本发明涉及从各种芳香烃混合物或从此类芳香烃和非芳香烃混合物中分离芳香烃的膜和方法。根据本发明，膜由芳香族聚酯在芳香族二酸氯化物的基础上与类似双酚 A 的双酚或完全由芳香族中心组成的双酚组合而成。 膜最好是由芳香族聚酯与对苯二甲酰氯、间苯二甲酰氯、5-t-丁基间苯二甲酰氯或 PIDA 等芳香族二酸酰氯以及 4X-BPN、4X-BPT、4X-BPI 等双酚-A 类双酚组合而成。