bis(4-nitrobenzoic 1,1-dimethylhydrazide)Cu(II) | 845963-20-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(4-nitrobenzoic 1,1-dimethylhydrazide)Cu(II)
• 英文别名: copper;(1Z)-N,N-dimethyl-4-nitrobenzenecarbohydrazonate
• CAS: 845963-20-4
• 化学式: C₁₈H₂₀CuN₆O₆
• 分子量: 479.939
• InChiKey: JOZNLFMMHXWQJW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 4-nitrobenzoic 1,1-dimethylhydrazide 以 乙醇 、 水 为溶剂， 生成 bis(4-nitrobenzoic 1,1-dimethylhydrazide)Cu(II)
  参考文献：
  名称：

  Complexes of Some 3d-Metal Salts with N,N-Dimethylhydrazide of 4-Nitrobenzoic Acid

  摘要：

  The [M(HL)(2)(H2O)(2)]X-2 complexes were synthesized(M = Mn(II), Co(II), Ni(II), Cu(II), Zn; X = CH3COO-, Cl-, BF4-) that incorporate bidentately coordinated molecules of N,N-dimethylhydrazide of 4-nitrobenzoic acid (HL). The latter molecules chelate the metal atom through the carbonyl O atom and the N atom of dimethylamino group. The square-planar complexes of Cu and Ni with deprotonated form of a ligand with composition ML2 were also isolated. The synthesized complexes were studied by IR, electronic and EPR spectroscopies, and by cyclic voltammetry.

  DOI：

  10.1023/b:ruco.0000043902.12955.5e