N-[[amino(pyridin-2-yl)methylidene]amino]-2-[[2-[2-[amino(pyridin-2-yl)methylidene]hydrazinyl]-2-oxoethyl]amino]acetamide | 583029-89-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-[[amino(pyridin-2-yl)methylidene]amino]-2-[[2-[2-[amino(pyridin-2-yl)methylidene]hydrazinyl]-2-oxoethyl]amino]acetamide
• CAS: 583029-89-4
• 化学式: C₁₆H₁₉N₉O₂
• 分子量: 369.386
• InChiKey: APCXSIWIDDMGHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  173
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  copper(II) nitrate trihydrate 、 N-[[amino(pyridin-2-yl)methylidene]amino]-2-[[2-[2-[amino(pyridin-2-yl)methylidene]hydrazinyl]-2-oxoethyl]amino]acetamide 以 甲醇 、 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Trinuclear complexes of a series of ‘tritopic’ hydrazide ligands—structural and magnetic properties

  摘要：

  Copper(II) and manganese(II) complexes of some new symmetric and asymmetric tritopic hydrazide ligands based on 2,6-pyridine-dihydrazide (L1, L2) and iminodiacetic acid dihydrazide (L3) have been studied. The linear trinuclear complexes [Cu-3(L1-3H)(CH3COO)(3)(H2O)(2)].H2O (1) and [Cu-3(L2-4H)(H2O)(3)(CH3OH)](NO3)(2) (3) have three copper(II) centers bridged by trans -N-N diazine linkages and exhibit moderate antiferromagnetic exchange. The complex [Mn-3(L3)(2)(CH3CN)(2)(H2O)(2)](ClO4)(6).2H(2)O (5) has an unusual trinuclear structure involving an alkoxy-bridged dinuclear center and an essentially isolated mononuclear Mn(II) center. The Mn(11) ions are antiferromagnetically coupled within the dinuclear subunit. Structural and magnetic data are discussed. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00069-x