Cu-[Salen-Br] | 34982-68-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu-[Salen-Br]
• CAS: 34982-68-8
• 化学式: C₁₆H₁₂Br₂CuN₂O₂
• 分子量: 487.637
• InChiKey: QNJYSSFNAACGTD-HCURTGQUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙二胺 、 以 乙醇 为溶剂， 生成 Cu-[Salen-Br]
  参考文献：
  名称：

  Tanaka, T., Bulletin of the Chemical Society of Japan, 1960, vol. 33, p. 259 - 261

  摘要：

  DOI：

文献信息

• The functionality of the hybrid systems driven by molecular dimension of the guest copper Schiff-base complexes entrapped in Zeolite-Y
  作者：Susheela Kumari、Archana Choudhary、Saumi Ray

  DOI：10.1002/aoc.4765

  日期：2019.3

  On encapsulation inside the supercage of zeolite‐Y planar Cu (II)–Schiff base complexes show the modified structural, optical and functional properties. The electronic effect of the different substituent groups present in the catalyst plays the decisive role towards their reactivity in the homogeneous phase but after the encapsulation in zeolite Y, reactivity is mainly governed by the molecular dimensions

  在沸石-Y平面Cu（II）-Schiff碱配合物的超笼中进行封装时，显示出修饰的结构，光学和功能特性。催化剂中存在的不同取代基的电子效应对其在均相中的反应性起决定性作用，但在将其包封在Y型沸石中后，反应性主要取决于客体配合物的分子尺寸，而不是分子的电子因素。取代基连接在其上。这些系统借助各种表征工具（例如XRD分析，SEM-EDX，AAS，FTIR，XPS，DSC，TGA，
• New Ni(II) and Cu(II) Schiff base coordination complexes derived from 5-Bromo-salicylaldehyde and 3-picoyl amine/ethylenediamine: Synthesis, structure, Hirshfeld surface and molecular docking study with SARS-CoV-2 7EFP-main protease
  作者：Aprajita、Mukesh Choudhary

  DOI：10.1016/j.poly.2023.116296

  日期：2023.3

  Two co-ordination compounds, one nickel(II) complex [Ni(L1)(Phen)2]ClO4 (1) and one copper(II) complex [Cu(L2)] (2), were synthesized using Schiff base ligands derived from the condensation reaction of 5-Bromo-salicylaldehyde with 3-picoyl amine (L1H)(L1H = (E)-4-Bromo-2-(((pyridin-3-ylmethylene)amino) methyl) phenol) and ethylenediamine (L2H2), respectively(L2H2 = 2,2′-((1E,1′E)-(ethane-1,2-diylb

  使用席夫法合成了两种配位化合物，一种是镍 (II) 络合物 [Ni(L 1 )(Phen) 2 ]ClO 4 (1)，另一种是铜 (II) 络合物 [Cu(L 2 )] (2)碱基配体衍生自 5-溴-水杨醛与 3-甲基吡啶胺 (L 1 H)(L 1 H = (E)-4-Bromo-2-(((pyridin-3-ylmethylene)amino)) 甲基的缩合反应)苯酚)和乙二胺(L 2 H 2 ),分别为(L 2 H 2 = 2,2'-((1E,1'E)-(ethane-1,2-diylbis(azanelylidene))bis(methanelylidene))bis (4-bromophenol))。对新合成的复合物进行了全面表征，包括 X 射线晶体学。使用单晶结构分析确定这两种复合物的晶体结构。(1)的电化学性质使用循环伏安法进行了研究。对新合成的配位络合物进行了 DFT 计算，
• Syntheses and characterization of copper(II) complexes with Schiff-base ligands derived from ethylenediamine, diphenylethylenediamine and nitro, bromo and methoxy salicylaldehyde
  作者：S Zolezzi、A Decinti、E Spodine

  DOI：10.1016/s0277-5387(98)00376-3

  日期：1999.1

  Copper(II) quelates with Schiff bases derived from ethylenediamine, 1R,2R-(+)- or 1S,2S-(-)-1,2-diphenylethylenediamine and 5-X-salicylaldehyde (X=OCH3, H, Br, NO2) have been synthesized and characterized by elemental analysis and IR and UV-visible spectroscopies. The ORD and CD spectra of the chiral ligands and their related complexes have also been measured. The absorption and CD spectra of the metal complexes in the visible region are consistent with near. square planar coordination geometries. Trends in absorption spectra over the series of complexes can be correlated with electronic effects of the substituents at position 5 of the salicylaldehyde. The sign patterns of the CD spectra in both UV and visible regions suggest the prevalence of S and A conformations for the chelate ring in the complexes of Schiff bases derived, respectively, from R,R- and S,S-diamines. Specific features of the CD spectra of the metal complexes are discussed in terms of the exciton chirality method. (C) 1999 Elsevier Science Ltd. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 173, page 1830 - 1832
  作者：

  DOI：——

  日期：——