bis{2-(m-tolylazo)pyridine}silver(I) perchlorate | 131972-14-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis{2-(m-tolylazo)pyridine}silver(I) perchlorate
• 英文别名: {Ag(2-(m-tolylazo)pyridine)2}ClO4
• CAS: 131972-14-0
• 化学式: Ag*2C₁₂H₁₁N₃*ClO₄
• 分子量: 601.798
• InChiKey: LIBDDMUATAUGAZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis{2-(m-tolylazo)pyridine}silver(I) perchlorate 、 dichlorobis(2-m-tolylazopyridine)chromium(II) 以 乙醇 为溶剂， 以75%的产率得到[Cr(2-m-tolylazopyridine)3]ClO4 * H2O
  参考文献：
  名称：

  Convenient Approach to the Direct Syntheses of Chromium Complexes from Chromium(III) Chloride

  摘要：

  Efficient, new and direct synthetic routes for the syntheses of chromium complexes of some N,N-donors, based on the reactions of a chromium(III) chloride salt and silver(I) complexes of the corresponding ligands, have been described. It has been shown that syntheses of mixed-ligand complexes of desired compositions may easily be achieved by following these trans-metalation reaction routes. Comparison of the synthetic methodology with the reported methods has been noted.

  DOI：

  10.1021/ic00118a035

文献信息

• Use of silver(I) complexes in synthesis of bis- and tris-[2-(arylazo)pyridine] complexes of ruthenium(II) and investigation of solid-state isomerisation
  作者：Alok K. Deb、Maushumi Kakoti、Sreebrata Goswami

  DOI：10.1039/dt9910003249

  日期：——

  direct synthetic routes to isomeric [RuCl2L2] and [RuL3][ClO4]2·H2O [L = 2-(arylazo)pyridine] complexes, based on the reaction of hydrated RuCl3 and [AgL2]ClO4, have been elaborated. The identity of the compounds were established from elemental analyses and spectral data. The advantages of the new methods are highlighted. Solid-state isomerisation of the dichloride complexes has been studied by different

  基于水合RuCl 3和水合RuCl 3与水的反应，可以高效，新颖和直接地合成异构体[RuCl 2 L 2 ]和[RuL 3 ] [ClO 4 ] 2 ·H 2 O [L = 2-（芳基偶氮）吡啶]配合物已经详细说明了[AgL 2 ] ClO 4。根据元素分析和光谱数据确定化合物的身份。强调了新方法的优点。已经通过不同的热方法研究了二氯化物配合物的固态异构化。结果表明，两（反式，反式及顺，顺加热后，[RuCl 2 L 2 ]的三种异构体中的）被转化为第三种（反式，顺式）异构体。差示扫描量热法数据的分析表明，热异构化反应通过相似的中间体进行。还简要指出了[RuCl 2 L 2 ]的不同异构体的相对热稳定性。
• A family of mixed ligand complexes of RuII-L [L = N-aryl-pyridine-2-aldimine], their reactions, isolation and characterization. X-ray crystal structure of [Ru(pic)(L1)2][ClO4]· CH2Cl2 [pic= 2-picolinate ion]
  作者：Kedar Nath Mitra、Subrata Choudhury、Sreebrata Goswami、Shie-Ming Peng

  DOI：10.1016/s0277-5387(96)00482-2

  日期：1997.3

  Abstract Synthesis of the tris-chelated complexes [Ru(L)n(L3)3−n]2+ (L= N-aryl-pyridine-2-aldimine, L3 = 2-(m-tolylazo)pyridine) based on silver(I) assisted trans-metallation is described. The complexes, [Ru(L)3]2+ and [Ru(L)(L3)2]2+ afford [Ru(pic)(L)2]+ and [Ru(pic)(L3)2]+ (pic= 2-picolinate ion) respectively, on hydrolysis and subsequent oxidation. When RuCl2(L)2 was reacted with two moles of [Ag(L3)2]+

  摘要基于银的三螯合配合物[Ru（L）n（L3）3-n] 2+（L = N-芳基吡啶-2-醛亚胺，L3 = 2-（间甲苯基）吡啶）的合成（I）描述了辅助的过渡金属化。[Ru（L）3] 2+和[Ru（L）（L3）2] 2+复合物提供[Ru（pic）（L）2] +和[Ru（pic）（L3）2] +（分别在水解和随后的氧化反应中得到（pic ＝ 2-吡啶甲酸离子）。当RuCl2（L）2与两摩尔[Ag（L3）2] +反应时，组成[Ru（L）（L3）（L4）] + [L4 = N-芳基-2-吡啶啉酰胺]的粉红色络合物分离出预期的棕色络合物[Ru（L3）（L）2] 2+。金属离子的初始氧化有利于L→L4转化。使用光谱学和X射线晶体学对复合物进行了表征。报告了[Ru（pic）（L1）2] ClO4·CH2Cl2的X射线结构。使用铂作为工作电极，在乙腈中通过伏安法研究了配合物的金属氧化和配体还原。已经观察到
• Kakoti, Maushumi; Deb, Alok K.; Goswami, Sreebrata, Inorganic Chemistry, 1992, vol. 31, # 7, p. 1302 - 1304
  作者：Kakoti, Maushumi、Deb, Alok K.、Goswami, Sreebrata

  DOI：——

  日期：——