N-[2,6-di(propan-2-yl)phenyl]-1-[6-(furan-2-yl)pyridin-2-yl]ethanimine | 565177-92-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-[2,6-di(propan-2-yl)phenyl]-1-[6-(furan-2-yl)pyridin-2-yl]ethanimine
• CAS: 565177-92-6
• 化学式: C₂₃H₂₆N₂O
• 分子量: 346.472
• InChiKey: DVFAHNMTTDUWLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  38.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 N-[2,6-di(propan-2-yl)phenyl]-1-[6-(furan-2-yl)pyridin-2-yl]ethanimine 以 正丁醇 为溶剂， 生成
  参考文献：
  名称：

  Selective Oligomerization of Ethylene to Linear α-Olefins by Tetrahedral Cobalt(II) Complexes with 6-(Organyl)-2-(imino)pyridyl Ligands:  Influence of the Heteroatom in the Organyl Group on the Catalytic Activity

  摘要：

  The oligomerization of ethylene to alpha-olefins has been obtained by MAO activation of tetrahedral Co-II complexes of iminopyridines substituted in the 6-position of the pyridine ring by thiophen-2-yl, furan-2-yl, or phenyl groups. An intriguing heteroatom effect has been noticed on both activity and selectivity, together with a change in the Co-II spin state upon activation of the dichloride precursors with MAO.

  DOI：

  10.1021/om030227d