tris(2,6-diisopropylphenoxy)(dimethyl(phenyl)-l5-phosphaneyl)tantalum(VI) hydride | 146053-93-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(2,6-diisopropylphenoxy)(dimethyl(phenyl)-l5-phosphaneyl)tantalum(VI) hydride
• CAS: 146053-93-2
• 化学式: C₄₄H₆₄O₃PTa
• 分子量: 852.912
• InChiKey: DQTXYBOKDAEKKY-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  12.84
• 重原子数：
  49.0
• 可旋转键数：
  14.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  27.69
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  三丁基膦 、 tris(2,6-diisopropylphenoxy)(dimethyl(phenyl)-l5-phosphaneyl)tantalum(VI) hydride 生成 tris(2,6-diisopropylphenoxy)(tributyl-l5-phosphaneyl)tantalum(VI) hydride
  参考文献：
  名称：

  Crystal and molecular structure of [Ta(H)2(OC6H3Pri 2-2,6)3(PMe2Ph)]: a distorted six-coordinate tantalum dihydride

  摘要：

  在磷配体（L）存在的情况下，[Ta(OC6H3Pri2-2,6)3R2](R = CH2C6H4-4-Me)与H2反应，生成二氢化物[Ta(H)2(OC6H3Pri2-2,6)3(L)]，PMe2Ph衍生物的固态结构显示，金属中心的几何结构严重偏离八面体；芳基膦和其他芳香族底物的氢化反应由这些二氢化物催化。

  DOI：

  10.1039/c39920001505
• 作为产物：
  描述：

  tris(2,6-diisopropylphenoxy)bis(4-methylbenzyl)tantalum 、 二甲基苯基磷 在 H₂ 作用下， 以 环己烷 为溶剂， 生成 tris(2,6-diisopropylphenoxy)(dimethyl(phenyl)-l5-phosphaneyl)tantalum(VI) hydride
  参考文献：
  名称：

  Crystal and molecular structure of [Ta(H)2(OC6H3Pri 2-2,6)3(PMe2Ph)]: a distorted six-coordinate tantalum dihydride

  摘要：

  在磷配体（L）存在的情况下，[Ta(OC6H3Pri2-2,6)3R2](R = CH2C6H4-4-Me)与H2反应，生成二氢化物[Ta(H)2(OC6H3Pri2-2,6)3(L)]，PMe2Ph衍生物的固态结构显示，金属中心的几何结构严重偏离八面体；芳基膦和其他芳香族底物的氢化反应由这些二氢化物催化。

  DOI：

  10.1039/c39920001505

文献信息

• Synthesis and Characterization of a Series of Mononuclear Tantalum(V) Hydride Compounds Containing Aryloxide Ligation
  作者：Bernardeta C. Parkin、Janet R. Clark、Valerie M. Visciglio、Phillip E. Fanwick、Ian P. Rothwell

  DOI：10.1021/om00006a051

  日期：1995.6

  A series of seven-coordinate, mononuclear tantalum-hydride compounds [Ta(OC6H3Pr2i-2,6)(2)-(Cl)(3-n)(H)(n)](1, n = 1; 2, n = 2; 3, n = 3; OC6H3Pr2i-2,6 = 2,6-diisopropylphenoxide; L = tertiary phosphines) can be obtained either by hydrogenolysis of the corresponding tantalum alkyl substrate, producing 2 and 3, or by reacting the trichloride [Ta(OC6H3Pr2i-2,6)(2)Cl-3] with one (for 1) or two (for 2) equiv of Bu(3)(n)SnH in the presence of ligand. The hydrogenolysis of the substrate [Ta(OC6H3Pr2i-2,6)(2)(CH2C6H4-4Me)(3)] in the presence of PMe(2)Ph or PMePh(2) produces the complexes [Ta(OC6H3Pr2i-2,6)(2)(H)(3)(L)(2)] (3a, L = PMe(2)Ph; 3b, L = PMePh(2)), while the compounds [Ta(OC(6)H(3)Ph(2)-2,6)(2)(R)(3)] (R = CH2C6H4-4Me, CH(2)SiMe(3)) produce [Ta(OC(6)H(3)Cy(2)-2,6)(2)(H)(3)(L)(2)] (3c, L = PMe(2)Ph; 3d, L = PMePh(2)) with the 2,6-dicyclohexylphenoxide ligand being generated by intramolecular hydrogenation of the ortho phenyl rings in the 2,6-diphenylphenoxide substrate. The hydrogenolysis of the bisalkyl [Ta(OC6H3Pri(2)-2,6)(3)(CH2C6H4-4Me)(2)] in the presence of PMe(2)-Ph produces the six-coordinate [Ta(OC6H3Pr2i-2,6)(3)(PMe(2)Ph)(H)(2)], 4b, which will exchange the phosphine ligand to produce a series of substituted derivatives. A related series of six-coordinate dihydride compounds [Ta(OC(6)H(3)Bu(2)(t)-2,6)(2)(L)(Cl)(H)(2)], 5, are produced by addition of Bu(n)SnH (2 Sn per Ta) to [Ta(OC(6)H(3)Bu(t)(2)-2,6)(2)Cl-3] in the presence of added L. Single-crystal X-ray diffraction analyses of seven-coordinate 1, 2b, and 3c (all cases L = PMe(2)Ph) show them to adopt pentagonal bipyramidal geometries with traits axial aryloxide ligands. In monohydride 1 the unique hydride ligand is cis to both phosphine ligand, while in dihydride 2b the hydride ligands are mutually cis but trans to the chloride group within the pentagonal plane. A crystallographic 2-fold axis in trihydride 3c passes through the unique Ta-H bond and bisects the remaining cis hydride ligands within the pentagonal plane. The solution H-1 NMR spectra of 1, 2, and 3 are consistent with the solid state structure being maintained in solution. Furthermore, analysis and simulation of the downfield hydride resonances in 2 and 3 show these seven-coordinate molecules to be stereochemically rigid on the NMR time scale. The coupling constants obtained from simulations conclusively rule out the formulation of 2 or 3 as containing eta(2)-H-2 ligands. The solid state structures of six-coordinate [Ta(OC6H3Pri(2)-2,6)(3)(PMe(2)Ph)(H)(2)], 4b, and [Ta(OC(6)H(3)Bu(2)(t)-2,6)(2)- (PMePh(2))(Cl)(H)(2)], 5c, show a geometry severely distorted from octahedral.In both compounds the mutually trans hydride ligands are bent toward the phosphine ligand with H-Ta-P angles of 66(2)degrees and 69(1)degrees for 4a and 56(2)degrees and 62(2)degrees for 5b. A steric origin to this distortion is ruled out by the structure of 5b in which the hydride ligands are bent toward the bulky phosphine ligand and away from the Ta-Cl bond. Strong support for the distorted structures of 4 and 5 comes from solution and solid state infrared spectra where two sharp <(nu)over bar>(Ta-H) vibrations are observed. Analysis ofthe intensity ratio for the symmetric and asymmetric bands yields predicted H-Ta-H angles very close to these observed in the solid state structure. The summary of the crystal data is as follows for [Ta(OC6H3Pr2i-2,6)(2)(PMe(2)Ph)(2)(Cl)(2)(H)], 1, at 20 degrees C: a = 26.025(4) Angstrom, b = 10.7954(5) Angstrom, c = 18.509(3) Angstrom, beta = 128.31(1)degrees, Z = 4, d(calcd) = 1.438 g cm(-3) in space group C2/c. For [Ta(OC6H3Pr2i-2,6)(2)(PMe(2)Ph)(2)(Cl)(H)(2)], 2b, at 20 degrees C: a = 9.735(1) Angstrom, b = 24.310(3) Angstrom, c = 17.735(2) Angstrom, beta = 90.76(1)degrees, Z = 4, d(calcd) = 1.344 g cm(-3) in space group P2(1)/n. For [Ta(OC(6)H(3)Cy(2)-2,6)(2)(PMe(2)Ph)(2)(H)(3)], 3c, at 20 degrees C: a = 24.065(3) Angstrom, b = 13.530(2) Angstrom, c = 20.263(3) Angstrom , beta = 131.633(9)degrees, Z = 4, d(calcd) = 1.313 g cm(-3) in space group C2/c. For [Ta(OC6H3Pr2i-2,6)(3)(PMe(2)Ph)(H)(2)], 4b, at 20 degrees C: a = 10.637(1) Angstrom, b = 12.820(2) Angstrom, c = 31.799(4) Angstrom, beta = 98.76(1)degrees, Z = 4, d(calcd) = 1.322 g cm(-3) in space group P2(1)/n. For [Ta(OC(6)H(3)But(2)-2,6)(2)(PMePh(2))(Cl)(H)(2)], 5c, at -100 degrees C, a = 10.851(5) Angstrom, b = 18.110(7) Angstrom, c = 20.09(1) Angstrom, beta = 96.67(5)degrees, Z = 4, d(calcd) = 1.404 g cm(-3) in space group P2(1)/n.