(1-(2-(benzyloxy)naphthalen-1-yl)naphthalen-2-yl)(phenyl)methanol | 1370021-72-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (1-(2-(benzyloxy)naphthalen-1-yl)naphthalen-2-yl)(phenyl)methanol
• CAS: 1370021-72-9
• 化学式: C₃₄H₂₆O₂
• 分子量: 466.579
• InChiKey: LIWAIBUHBDKLSO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-[2-[Hydroxy(phenyl)methyl]naphthalen-1-yl]naphthalen-2-ol 、 溴甲苯 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 6.5h， 以86%的产率得到(1-(2-(benzyloxy)naphthalen-1-yl)naphthalen-2-yl)(phenyl)methanol
  参考文献：
  名称：

  A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc

  摘要：

  We report here the first example of the reduction of acylsilanes to alpha-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)(4) or other Lewis acids. The reduction typically proceeds to give synthetically useful alpha-hydroxysilanes in good yields. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.02.059
• 作为试剂：
  描述：

  硅烷,苯甲酰(1,1-二甲基乙基)二甲基- 在 titanium(IV) isopropylate 、 (1-(2-(benzyloxy)naphthalen-1-yl)naphthalen-2-yl)(phenyl)methanol 、 diethylzinc 、 盐酸 作用下， 以 乙醚 、 正己烷 、 水 为溶剂， 反应 12.0h， 生成 (S)-1-phenyl-1-(tert-butyldimethylsilyl)methanol 、 (R)-1-phenyl-1-(tert-butyldimethylsilyl)methanol
  参考文献：
  名称：

  A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc

  摘要：

  We report here the first example of the reduction of acylsilanes to alpha-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)(4) or other Lewis acids. The reduction typically proceeds to give synthetically useful alpha-hydroxysilanes in good yields. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.02.059