| 940968-62-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 940968-62-7
• 化学式: CH₂Cl₂*C₅₂H₄₀N₂O₂P₂Pd
• 分子量: 978.202
• InChiKey: HHRKOKINGXWSLK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯甲烷 、 2-(diphenylphosphanyl)-N-(2-{[2-(diphenylphosphanyl)phenyl]formamido}-1,2-diphenylethyl)benzamide 、 palladium diacetate 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以92.7%的产率得到
  参考文献：
  名称：

  Tetracoordinate diamidato-bis(phosphanyl) metal systems: Synthesis, characterization, and electrochemical analysis of palladium(II) complexes

  摘要：

  Square planar diamidato-bis(phosphanyl) palladium(II) complexes have been prepared and characterized. Most products precipitate out of THF solution on reaction of the parent ligand with Pd(OAc)(2) in the presence of 2 equiv. of base at 50 degrees C overnight. The solution and solid state structure of each complex is reported based on multinuclear NMR and X-ray analyses, respectively. The effects of carboxamido nitrogen coordination on the stabilization of the metal center from reduction were studied using cyclic voltammetry. The irreversible peak reduction potential of each complex was greater by approximately -340 mV to -590 mV as compared to Pd(PPh3)(2)Cl-2 indicating that carboxamido nitrogen coordination protects the Pd(II) center from reduction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.011