N-dichloroacetyl-2,2-diethyl-1,3-oxazolidine | 104767-35-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: N-dichloroacetyl-2,2-diethyl-1,3-oxazolidine
• 英文别名: 2,2-Dichloro-1-(2,2-diethyl-1,3-oxazolidin-3-yl)ethanone
• CAS: 104767-35-3
• 化学式: C₉H₁₅Cl₂NO₂
• 分子量: 240.13
• InChiKey: ZSEFXOWWFZLCGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二氯乙酰氯 、 2,2-diethyloxazolidine 在 sodium hydroxide 作用下， 以 水 、 苯 为溶剂， 生成 N-dichloroacetyl-2,2-diethyl-1,3-oxazolidine
  参考文献：
  名称：

  A convenient synthesis of novelN-dichloroacetyl-1,3-oxazolidine

  摘要：

  Abstract magnified imageA short and efficient route of synthesis and structural characterization of a series of novel N‐dichloroacetyl‐1,3‐oxazolidine derivatives has been developed. These new compounds characterized of the disubstitution at position 2 by alkyl, cycloalkane, and phenyl were synthesized in good yields via a sequential procedure involving condensation and acylation. All the compounds are characterized by IR, 1H NMR, 13C NMR, and element analysis. J. Heterocyclic Chem., (2010).

  DOI：

  10.1002/jhet.289

文献信息

• PYRIMIDIN-4-YLPROPANEDINITRILE DERIVATIVES, PROCESSES FOR THEIR PREPARATION AND THEIR USE AS HERBICIDES AND PLANT GROWTH REGULATORS
  申请人：Brünjes Marco

  公开号：US20100240536A1

  公开（公告）日：2010-09-23

  Pyrimidin-4-ylpropanedinitrile derivatives, process for their preparation and their use as herbicides and plant growth regulators The invention relates to compounds of the formula (I) and N-oxides, tautomers and agrochemically compatible salts thereof to processes for their preparation, and to their use as herbicides and plant growth regulators, in particular as herbicides for the selected control of harmful plants in useful plant crops.

  本发明涉及公式（I）和其N-氧化物、互变异构体及其农药兼容盐，以及它们的制备方法和用作除草剂和植物生长调节剂，特别是用作在有用植物作物中选择性控制有害植物的除草剂。其中，化合物为嘧啶-4-基丙烷二腈衍生物。
• US8309557B2
  申请人：——

  公开号：US8309557B2

  公开（公告）日：2012-11-13