p-ethylphenyl(phenoxy)thiophosphonic acid hydrazide | 689284-94-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-ethylphenyl(phenoxy)thiophosphonic acid hydrazide
• CAS: 689284-94-4
• 化学式: C₁₄H₁₇N₂OPS
• 分子量: 292.342
• InChiKey: URZYNAWGYAPADZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.73
• 重原子数：
  19.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  47.28
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate 、 p-ethylphenyl(phenoxy)thiophosphonic acid hydrazide 以 氯仿 为溶剂， 以56%的产率得到4-[2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl]-1-[p-ethylphenyl(phenoxy)thiophosphoryl]thiosemicarbazide
  参考文献：
  名称：

  Synthesis of O-Aryl N⁴-Glycosyl(thiosemicarbazido)phosphonothioates

  摘要：

  A reaction of aryl(aryloxy)thiophosphonic acids hydrazides with glycosyl isothiocyanates was studied. Amides of N-(glycosylthioureylene)aryl(aryloxy)thiophosphonic acids were synthesized. The structure and composition of the new compounds were confirmed by the data of IR, H-1 and P-31 NMR and mass spectra, and by results of elemental analyses.

  DOI：

  10.1023/b:rujo.0000013135.25430.40
• 作为产物：
  描述：

  苯酚 、 Dichloro-(4-ethylphenyl)-sulfanylidene-lambda5-phosphane 在 一水合肼 作用下， 以72%的产率得到p-ethylphenyl(phenoxy)thiophosphonic acid hydrazide
  参考文献：
  名称：

  Synthesis of O-Aryl N⁴-Glycosyl(thiosemicarbazido)phosphonothioates

  摘要：

  A reaction of aryl(aryloxy)thiophosphonic acids hydrazides with glycosyl isothiocyanates was studied. Amides of N-(glycosylthioureylene)aryl(aryloxy)thiophosphonic acids were synthesized. The structure and composition of the new compounds were confirmed by the data of IR, H-1 and P-31 NMR and mass spectra, and by results of elemental analyses.

  DOI：

  10.1023/b:rujo.0000013135.25430.40