(S)-(3-hydroxypent-1-yn-1-yl)(tricyclohexyl-l5-phosphaneyl)gold | 860453-10-7

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: (S)-(3-hydroxypent-1-yn-1-yl)(tricyclohexyl-l5-phosphaneyl)gold
• CAS: 860453-10-7
• 化学式: C₂₃H₄₀AuOP
• 分子量: 560.51
• InChiKey: PWZDPERIAYEYSQ-NXAOXGSFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙基乙炔基甲醇 在 KBr 、 SO₂ 作用下， 以 水 、 丙酮 、 甲苯 为溶剂， 生成 (S)-(3-hydroxypent-1-yn-1-yl)(tricyclohexyl-l5-phosphaneyl)gold
  参考文献：
  名称：

  Use of phosphine gold acetylides [(R3P)AuCCR] to form phosphine gold derivatives of tetra-iron and penta-iron clusters

  摘要：

  Five new gold acetylides, [AuC equivalent to CR], with hydroxyl or amino functions in the organic radical R have been prepared. From these, nine phosphine complexes [(R3P)AuC equivalent to CR] with R = Ph or Cy were synthesised. Reactions between the phosphine gold acetylides [(Ph3P)AuC equivalent to CC(Me)(OH)Et] or [(Cy3P)AuC equivalent to CC(Me)(OH)Et] and the iron carbonyl cluster [Et4N][Fe4N(CO)(12)] gave both neutral [(R3P)AuFe4N(CO)(12)] and ionic compounds [(R3P)(2)Au][Fe4N(CO)(12)]. Reaction with the penta-iron cluster [Et4N][Fe5N(CO)(14)] afforded [(R3P)(2)Au][Fe5N(CO)(14)], [(R3P)(2)Au][Fe4N(CO)(12)] and [(R3P)AuFe4N(CO)(12)]. The gold-iron clusters were characterised with spectroscopic methods (IR, NMR and Mossbauer) and in the case Of [(Cy3P)AuFe4N(CO)(12)] a single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.045