dimethyl 4-((E)-(4-(dimethylamino)phenyl)iminomethyl)pyridine-2,6-dicarboxylate | 1146950-86-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: dimethyl 4-((E)-(4-(dimethylamino)phenyl)iminomethyl)pyridine-2,6-dicarboxylate
• CAS: 1146950-86-8
• 化学式: C₁₈H₁₉N₃O₄
• 分子量: 341.367
• InChiKey: MFZYCTYNUMROEJ-YBFXNURJSA-N

物化性质

• 熔点：
  192-193 °C(Solvent: Ethanol)
• 沸点：
  520.4±50.0 °C(predicted)
• 密度：
  1.17±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.47
• 重原子数：
  25.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  81.09
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  dimethyl 4-formylpyridine-2,6-dicarboxylate 、 N,N-二甲基-对苯二胺 以 乙醇 为溶剂， 以85%的产率得到dimethyl 4-((E)-(4-(dimethylamino)phenyl)iminomethyl)pyridine-2,6-dicarboxylate
  参考文献：
  名称：

  Synthesis of Novel Donor–π–Acceptor Chromophores with Dipicolinate as Acceptor

  摘要：

  Three novel donor--acceptor (D--A) chromophores, with dipicolinate as acceptor, have been synthesized. All the compounds were characterized by 1H NMR, infrared (IR) spectroscopy, mass spectrometry (MS), and elemental analysis.

  DOI：

  10.1080/00397910802531963

文献信息

• Dipicolinate as acceptor in D–π–A chromophores: synthesis, characterization and fluorescence following single- and two-photon excitation
  作者：Haibo Xiao、Xiaoming Tao、Yaochuan Wang、Shixiong Qian、Guanghao Shi、Hui Li

  DOI：10.1016/j.tetlet.2008.09.073

  日期：2008.11

  Three novel donor-pi-acceptor type compounds with dipicolinate as acceptor have been synthesized. Their absorption, photoluminescence as well as their two-photon absorption properties have been investigated. Two of them show strong two-photon absorption and two-photon excited Up-conversion fluorescence. (C) 2008 Elsevier Ltd. All rights reserved.