| 1418757-11-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1418757-11-5
• 化学式: C₂₁H₃₄CoNOP₂
• 分子量: 437.448
• InChiKey: PYYRZYRSAWRPHU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  CoMe3(PMe3)3 、 2-氨基二苯甲酮 以 四氢呋喃 为溶剂， 反应 72.0h， 以72%的产率得到
  参考文献：
  名称：

  N–H bond activation of 2-aminobenzophenone by trimethylphosphine complexes of nickel and cobalt

  摘要：

  2-Aminobenzophenone (1) reacted with NiMe2(PMe3)(3) and CoMe3(PMe3)(3) afforded N-H bond cleavage products, the tetra-coordinate square-planar nickel complex (o-NH-c(6)H(4)-C(=O)-C6H5)NiMe(PMe3) (2), and the hexa-coordinate octahedral dimethyl cobalt(III) complex (o-NH-C6H4-C(=O)-C6H5)CoMe2(PMe3)(2) (3) with a cationic [N, O]-chelate ligand while the reaction of Co(PMe3)(4) with 2-aminobenzophenone (1) delivered only a pi-(C=0) coordinate complex (o-NH-C6H4-eta(2)-C(=O)-C6H5)Co(PMe3)(3) (4) in a tetrahedral coordination geometry. The structures of complexes 2-4 were determined by X-ray single crystal diffraction. The formation mechanism of complex 2 was discussed. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.12.005