(2,3-bis(3,5-dimethylphenylimino)butane)Pt(CH2SiMe3)2 | 550372-86-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,3-bis(3,5-dimethylphenylimino)butane)Pt(CH2SiMe3)2
• CAS: 550372-86-6
• 化学式: C₂₈H₄₆N₂PtSi₂
• 分子量: 661.938
• InChiKey: SIHVCLZFWCQEDR-GMLGPFLOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,3-bis(3,5-dimethylphenylimino)butane)Pt(CH2SiMe3)2 、 三(五氟苯基)硼烷 、 2,2,2-三氟乙醇-d3 以 further solvent(s) 为溶剂， 生成 [(2,3-bis(3,5-dimethylphenylimino)butane)PtMe(2,2,2-trifluoroethanol-d3)][(CF3CD2O)B(C6F5)3]
  参考文献：
  名称：

  Catalytic Alcoholysis of Tetramethylsilane via Pt-Mediated C−H Bond Activation

  摘要：

  Tetramethylsilane reacts with 2,2,2-trifluoroethanol (TFE) in the presence of a cationic platinum(II) catalyst [(NN)PtMe(TFE)]+ (NN = 1,2-bis(3,5-dimethylphenylimino)butane). Catalytic Si-C bond heterolysis results in the formation of the trimethylsilyl ether, Me3SiOCH2CF3, accompanied by liberation of one equivalent of methane. Preliminary experiments suggest that a rate-determining C-H bond activation precedes rapid attack by solvent at silicon to yield the silyl ether product and regenerate the active platinum methyl cation.

  DOI：

  10.1021/ja029099v
• 作为产物：
  描述：

  dichlorobis(dimethylsulfide)platinum(II) 、 2,3-bis(3,5-dimethylphenylimino)butane 、 trimethylsilylmethyllithium 以 not given 为溶剂， 生成 (2,3-bis(3,5-dimethylphenylimino)butane)Pt(CH2SiMe3)2
  参考文献：
  名称：

  Catalytic Alcoholysis of Tetramethylsilane via Pt-Mediated C−H Bond Activation

  摘要：

  Tetramethylsilane reacts with 2,2,2-trifluoroethanol (TFE) in the presence of a cationic platinum(II) catalyst [(NN)PtMe(TFE)]+ (NN = 1,2-bis(3,5-dimethylphenylimino)butane). Catalytic Si-C bond heterolysis results in the formation of the trimethylsilyl ether, Me3SiOCH2CF3, accompanied by liberation of one equivalent of methane. Preliminary experiments suggest that a rate-determining C-H bond activation precedes rapid attack by solvent at silicon to yield the silyl ether product and regenerate the active platinum methyl cation.

  DOI：

  10.1021/ja029099v