[Cu2Cl4(1-methylbenzotriazole)4] | 166267-36-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: [Cu2Cl4(1-methylbenzotriazole)4]
• 英文别名: dichlorocopper;1-methylbenzotriazole
• CAS: 166267-36-3
• 化学式: C₂₈H₂₈Cl₄Cu₂N₁₂
• 分子量: 801.515
• InChiKey: BHBPAABHVWEVTG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu2Cl4(1-methylbenzotriazole)4] 以 neat (no solvent) 为溶剂， 生成 [Cu2Cl4(1-methylbenzotriazole)2]n
  参考文献：
  名称：

  Copper(II) chloride–1-methylbenzotriazole chemistry: variation of product as a function of metal-to-ligand reaction ratio; synthesis, structure and properties of a dinuclear complex and a novel chain polymer with two alternating chromophores

  摘要：

  The 1:2 and 1:1 reactions of CuCl2 with 1-methylbenzotriazole in EtOH-CH(OEt)(3) gave the doubly chloro-bridged dimer [Cu2Cl4(C7H7N3)(4)] 1 and the novel alternating linear-chain polymer [{Cu2Cl4(C7H7N3)(2)}(n)] 2 respectively, crystal structures of which have been determined; magnetic susceptibility studies show that complex 1 possesses intramolecular- and complex 2 intrachain-ferromagnetic coupling.

  DOI：

  10.1039/dt9950002317
• 作为产物：
  描述：

  1-甲基苯并三唑 、 copper dichloride 在 HC(OEt)3 作用下， 以 乙醇 为溶剂， 以45%的产率得到[Cu2Cl4(1-methylbenzotriazole)4]
  参考文献：
  名称：

  Copper(II) chloride–1-methylbenzotriazole chemistry: variation of product as a function of metal-to-ligand reaction ratio; synthesis, structure and properties of a dinuclear complex and a novel chain polymer with two alternating chromophores

  摘要：

  The 1:2 and 1:1 reactions of CuCl2 with 1-methylbenzotriazole in EtOH-CH(OEt)(3) gave the doubly chloro-bridged dimer [Cu2Cl4(C7H7N3)(4)] 1 and the novel alternating linear-chain polymer [{Cu2Cl4(C7H7N3)(2)}(n)] 2 respectively, crystal structures of which have been determined; magnetic susceptibility studies show that complex 1 possesses intramolecular- and complex 2 intrachain-ferromagnetic coupling.

  DOI：

  10.1039/dt9950002317