dichloroplatinum;1-dicyclohexylphosphanyl-N-(dicyclohexylphosphanylmethyl)-N-methylmethanamine | 163353-98-8

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: dichloroplatinum;1-dicyclohexylphosphanyl-N-(dicyclohexylphosphanylmethyl)-N-methylmethanamine
• CAS: 163353-98-8
• 化学式: C₂₇H₅₁Cl₂NP₂Pt
• 分子量: 717.642
• InChiKey: OMDLFDWJOFCIMO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloroplatinum;1-dicyclohexylphosphanyl-N-(dicyclohexylphosphanylmethyl)-N-methylmethanamine 、 silver trifluoroacetate 以 二氯甲烷 为溶剂， 以94.2%的产率得到1-dicyclohexylphosphanyl-N-(dicyclohexylphosphanylmethyl)-N-methylmethanamine;platinum(2+);2,2,2-trifluoroacetate
  参考文献：
  名称：

  Synthesis of some Platinum(II) Diphosphine Complexes of the Type [PtX₂(P-P)] (X₂= CO₃; X = CH₃COO, CF₃COO, NCO)

  摘要：

  Treatment of aminobis(methylphosphine) complexes of platinum(II) with silver(I) salts in dichloromethane gives corresponding platinum(II) complexes of the type [PtX(2)(P-P)] where X(2) = CO3; X = CH3COO, CF3COO, NCO; P-P = (Cy(2)PCH(2))(2)NMe, dcpam; (Ph(2)PCH(2))(2)NMe, dppam). The complexes have been characterised by using spectroscopic techniques such as P-31-{H-1} and H-1 NMR, IR, and mass spectrometry.

  DOI：

  10.1080/00945719708000183
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 N,N-bis(dicyclohexylphosphinomethyl)methylamine 以 not given 为溶剂， 生成 dichloroplatinum;1-dicyclohexylphosphanyl-N-(dicyclohexylphosphanylmethyl)-N-methylmethanamine
  参考文献：
  名称：

  Synthesis of some Platinum(II) Diphosphine Complexes of the Type [PtX₂(P-P)] (X₂= CO₃; X = CH₃COO, CF₃COO, NCO)

  摘要：

  Treatment of aminobis(methylphosphine) complexes of platinum(II) with silver(I) salts in dichloromethane gives corresponding platinum(II) complexes of the type [PtX(2)(P-P)] where X(2) = CO3; X = CH3COO, CF3COO, NCO; P-P = (Cy(2)PCH(2))(2)NMe, dcpam; (Ph(2)PCH(2))(2)NMe, dppam). The complexes have been characterised by using spectroscopic techniques such as P-31-{H-1} and H-1 NMR, IR, and mass spectrometry.

  DOI：

  10.1080/00945719708000183