bis(2-mercaptopyridinato)bis(triphenylphosphine)ruthenium(II) | 30227-49-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bis(2-mercaptopyridinato)bis(triphenylphosphine)ruthenium(II)
• 英文别名: [Ru(pyridine-2-thione-H)2(triphenylphosphine)2]；[Ru(pyS)2(PPh3)2]；pyridine-2-thiolate;ruthenium(2+);triphenylphosphane
• CAS: 30227-49-7；35762-61-9
• 化学式: C₄₆H₃₈N₂P₂RuS₂
• 分子量: 845.971
• InChiKey: VNCKISUMBDLVEJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(2-mercaptopyridinato)bis(triphenylphosphine)ruthenium(II) 在 1,2-bis(diphenylphosphino)ethane 作用下， 以 甲苯 为溶剂， 生成 2-diphenylphosphanylethyl(diphenyl)phosphane;pyridine-2-thiolate;ruthenium(2+)
  参考文献：
  名称：

  Crystal structure of [bis 1,2-(diphenylphosphino)ethane]-bis(pyridine-2-thiolato)ruthenium(II)

  摘要：

  The Ru atom in the title compound, [Ru(dppe)(2-pyS)2] exists in a distorted octahedral geometry defined by a dppe ligand and two 2-pyS anions which function as bidentate ligands via their N- and S- atoms. Important interatomic parameters are Ru-P 2.240(3), 2.256(3); Ru-N 2.131(8), 2.136(8); Ru-S 2.413(3), 2.428(3) angstrom; P-Ru-P 84.1(1), S-Ru-S 155.0(1) and N-Ru-N 87.5(3)-degrees. Crystals are monoclinic, space group P2(1)/c, with unit cell dimensions a = 10.342(1), b = 31.145(6), c = 11.107(2) angstrom, beta = 113.80(1)-degrees and Z = 4. The structure was refined to final R = 0.064 for 3057 reflections with 1 greater-than-or-equal-to 2.5-sigma(I).

  DOI：

  10.1007/bf01161066
• 作为产物：
  描述：

  2-巯基吡啶 、 [RuH2(PPh3)4] 以 苯 为溶剂， 以94%的产率得到bis(2-mercaptopyridinato)bis(triphenylphosphine)ruthenium(II)
  参考文献：
  名称：

  铂金属的配合物。第29部分。钌和的吡啶-2-硫醇盐衍生物：[Ru（C 5 H 4 NS）2（CO）2（PPh 3）]和[Ru（C 5 H 4 NS）2的X射线晶体结构（CO）（PPh 3）]

  摘要：

  钌和前体[MH（Cl）（CO）（PPh 3）3 ]，[MH 2（CO）（PPh 3）3 ]，[Ru（CO）3（PPh 3）2 ]，[OsH 2（CO ）2（PPh 3）2 ]，[RuH 2（PPh 3）4 ]和[OsH 4（PPh 3）3 ]与吡啶-2-硫醇（pySH）或二吡啶基2,2'-二硫化物（pySSpy ）在沸腾的苯或甲苯中制得一系列吡啶-2-硫醇盐配合物，包括[MCl（pyS）（CO）（PPh 3）2]，（2个异构体），[M（pyS）2（CO）2（PPh 3）]，[M（pyS）2（CO）（PPh 3）]和[M（pyS）2（PPh 3）2 ]，其中吡啶-2-硫醇盐配体以单齿（S键）或双齿（N，S螯合）模式结合。在三乙胺和吡啶-2-硫醇的存在下，从[RuCl 2（PPh 3）3 ]和[RuCl 2（CO）2（PPh 3）2 ]获得相似的产物。新的络合物的特征是ir和nmr（31 P-

  DOI：

  10.1039/dt9850002101

文献信息

• Chemistry of pyridinethiols and related ligands—4.1 Complexes of bis(pyridine-2-thiolato- or 1-oxopyridine-2-thione) ruthenium(II) with bis(diphenylphosphino)alkanes
  作者：Tarlok S. Lobana、Randhir Singh

  DOI：10.1016/0277-5387(94)00317-8

  日期：1995.4

  obtained by the reactions of (i) RuL n Cl 2 [ n = 2 for L ( m = 1, 3) or n = 1.5 for L ( m = 4)] with HA ligands in the presence of triethylamine, (ii) RuA 2 (PPh 3 ) 2 with L ( m = 2; triphos; HA = C 5 H 5 NS), or (iii) RuCl 2 (PPh 3 ) 3 with C 5 H 5 NOS and L ( m = 2; triphos) in the presence of triethylamine and characterized using analytical data, IR, far-IR, UV-vis, 1 H and 13 C NMR, and cyclic

  摘要一系列含有2（1H）-吡啶硫酮（C 5 H 5 NS）或1-羟基吡啶-2-硫酮（C 5 H 5 NOS）和双（二苯基膦基）烷烃的钌（II）混合配体配合物，Ph 2 P（CH 2）m PPh 2（m = 1-4）和三叔膦（Ph 2 PCH 2 CH 2）2 PPh（triphOS），化学计量：RuA 2 L（HA = C 5 H 5 NS或C已经制备了5 H 5 NOS； L ＝二或三叔膦。配合物是通过（i）RuL n Cl 2 [对于L（m = 1，3）等于n = 2或对于L（m = 4）而言n = 1.5）与HA配体在三乙胺存在下的反应获得的， ii）具有L（m = 2; triphOS; HA = C 5 H 5 NS）的RuA 2（PPh 3）2或（iii）具有C 5 H 5 NOS和L（m = 2的RuCl 2（PPh 3）3 ；在三乙胺存在下，用分析数据，IR，远红外，UV-vis，1
• Reactions of dihydridotetrakis(triphenylphosphine)ruthenium(II) with N, O, and S ligands
  作者：Ricardo Obeso Rosete、David J. Cole-Hamilton、Geoffrey Wilkinson

  DOI：10.1039/dt9790001618

  日期：——

  The interaction of dihydridotetrakis(triphenylphosphine)ruthenium(II), RuH2(PPh3)4, with the following compounds has been studied: 2,2′-bipyridyl, o-dicyanobenzene, 2-hydroxypyridine, 8-hydroxyquinoline, 2-aminopyridine, 2-mercaptopyridine, o-phenylenediamine, 2-aminothiophenol, 2-aminophenol, pyrocatechol, resorcinol, and hydroquinone.

  研究了二氢化四（三苯基膦）钌（II），RuH 2（PPh 3）4与以下化合物的相互作用：2,2'-联吡啶基，邻二氰基苯，2-羟基吡啶，8-羟基喹啉，2-氨基吡啶，2-巯基吡啶，邻苯二胺，2-氨基苯硫酚，2-氨基苯酚，邻苯二酚，间苯二酚和对苯二酚。
• Platinum group metal chelates derived from 2-mercapto-, 2-hydroxy- and 2-amino-pyridines and -pyrimidines
  作者：Vart Alteparmakian、Pasquale Mura、Bruce G. Olby、Stephen D. Robinson

  DOI：10.1016/s0020-1693(00)83774-3

  日期：1985.10
• Lobana, Tarlok S.; Verma, Renu, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2003, vol. 42, # 3, p. 534 - 536
  作者：Lobana, Tarlok S.、Verma, Renu

  DOI：——

  日期：——
• Synthesis and characterization of ruthenium and osmium complexes of heterocyclic bidentate ligands (N,X), X=S, Se
  作者：Antonio Sousa-Pedrares、Maria Luz Durán、Jaime Romero、José Arturo García-Vázquez、Juan C. Monteagudo、Antonio Sousa、Jonathan R. Dilworth

  DOI：10.1016/j.ica.2005.06.009

  日期：2006.2

  The reaction of [RuCl2(PPh3)(3)] and [OsBr2(PPh3)(3)] precursors with a series of heterocyclic bidentate (N, X) ligands, X = S, Se, gave complexes [M(R-pyS)(2)(PPh3)(2)], (R = H, 3-CF3, 5-CF3, 3-Me3Si);[M(R-pymS)(2)(PPh3)(2)], (R = 4-CF3, 4,6-MeCF3) and [M(R-pySe)(2)(PPh3)(2)], (R = H, 3-CF3, 5-CF3) where M is Ru or Os, pyS and pymS the anions of pyridine-2-thione and pyrimidine-2-thione,respectively, and pySe is the anion produced by the reductive cleavage of the Se-Se bond in the dipyridyl-2,2'-diselenide. All of the compounds obtained were characterized by microanalysis, IR, FAB, NMR spectroscopy and by cyclic voltammetry. Compounds [Ru(3-CF3-pyS)(2)(PPh3)(2)]center dot 2(CH2Cl2) (2), [Ru(3-Me3Si-pyS)(2)(PPh3)(2)] (4), [Ru(4-CF3-pymS)(2)(PPh3)(2)] (5), [Ru(3-CF3-pySe)(2)(PPh3)(2)]center dot 2(CH2Cl2) (8), [Os(3-CF3-pyS)(2)(PPh3)(2)]center dot(CHCl3) (11), [Os(3-Me3Si-PYS)(2)(PPh3)(2)](13), [Os(3-CF3-pySe)(2)(PPh3)(2)]center dot 2(CH2Cl2) (17), [Os(5-CF3-pySe)(2)(PPh3)(2)]center dot(2)(H2O) (18) and [OSCl2(4,6-MeCF3-pymS)(PPh3)(2)](19) were also characterized by X-ray diffraction. In all cases, the metal is in a distorted octahedral environment with the heterocyclic ligand acting as a bidentate (N, S) chelate system. (c) 2005 Elsevier B.V. All rights reserved.