(5-(4-(10-hydroxy-1-decyloxy)phenyl)-10,15,20-tris-(2,4,6-trimethylphenyl)porphyrin)cobalt | 1361056-39-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (5-(4-(10-hydroxy-1-decyloxy)phenyl)-10,15,20-tris-(2,4,6-trimethylphenyl)porphyrin)cobalt
• 英文别名: (TMP-OH)Co
• CAS: 1361056-39-4
• 化学式: C₆₃H₆₆CoN₄O₂
• 分子量: 970.236
• InChiKey: CZJCKAJMPBDZBH-MAPLFIASSA-N

反应信息

• 作为反应物：
  描述：

  (5-(4-(10-hydroxy-1-decyloxy)phenyl)-10,15,20-tris-(2,4,6-trimethylphenyl)porphyrin)cobalt 、 碘甲烷 在 sodium amalgam 作用下， 以 四氢呋喃 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Photo-cleavage of the cobalt–carbon bond: visible light-induced living radical polymerization mediated by organo-cobalt porphyrins

  摘要：

  This article describes the photo-induced living radical polymerization of acrylamides mediated by organo-cobalt porphyrins through photo-cleavage of the Co–C bond to give organic radicals, which propagate polymerization, and cobalt(II), which is a persistent metal-centered radical. Photo stimulus controls the initiation steps and regulates chain growth by activating the Co–C bond.

  DOI：

  10.1039/c3cc41466c