[(Cy3P)2Pt(CO)] | 1265905-14-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: [(Cy3P)2Pt(CO)]
• 英文别名: carbon monoxide;platinum;tricyclohexylphosphane
• CAS: 1265905-14-3
• 化学式: C₃₇H₆₆OP₂Pt
• 分子量: 783.958
• InChiKey: YBSYCFHAWURBDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.89
• 重原子数：
  41
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  双(三环己基膦)铂(0) 、 (pentamethylcyclopentadienyl)(dicarbonyl)iridium(I) 以 苯 为溶剂， 以31%的产率得到[(Cy3P)2Pt(CO)]
  参考文献：
  名称：

  Carbonyl Complexes of Platinum(0): Synthesis and Structure of [(Cy₃P)₂Pt(CO)] and [(Cy₃P)₂Pt(CO)₂]

  摘要：

  The platinum(0) monocarbonyl complex, [(Cy3P)(2)Pt(CO)], was synthesized by reaction of [(Cy3P)(2)Pt] with [(eta(5)-C5Me5)Ir(CO)(2)] and subsequent irradiation. X-ray structure analysis was performed and represents the first structural evidence of a platinum(0) monocarbonyl complex bearing two free phosphine ligands. Its corresponding dicarbonyl complex [(Cy3P)(2)Pt(CO)(2)] was synthesized by treatment of [(Cy3P)(2)Pt] with CO at -40 degrees C and confirmed by X-ray structure analysis.

  DOI：

  10.1021/ic102200t