[lead(II)(tetrafluoroterephthalate)(DMF)(methanol)] | 1221409-61-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [lead(II)(tetrafluoroterephthalate)(DMF)(methanol)]
• CAS: 1221409-61-5
• 化学式: CH₄O*C₃H₇NO*C₈F₄O₄*Pb
• 分子量: 548.416
• InChiKey: ORTIHCXGIZRGIN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.1
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  120.8
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  甲醇 、 lead(II) nitrate 、 2,3,5,6-四氟对苯二甲酸 、 N,N-二甲基甲酰胺 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 以45%的产率得到[lead(II)(tetrafluoroterephthalate)(DMF)(methanol)]
  参考文献：
  名称：

  Two rod-based 3-D lead(II) tetrafluoroterephthalate coordination frameworks with sra topology: Syntheses, structures, and properties

  摘要：

  Two three-dimensional (3-D) Pb-II coordination frameworks [Pb(BDC-F-4)(CH3OH)](n) (1) and [Pb(BDC-F-4)(DMF)(CH3OH)](n) (2) have been prepared by the reactions of Pb(NO3)(2) with a rigid dicarboxyl compound tetrafluoroterephthalic acid (H2BDC-F-4) in different solvents. Single crystal X-ray diffraction reveals that both complexes show the unusual rod-based coordination networks with sra topology, although they crystallize in different space groups (C2/c and P (1) over bar). Their spectroscopic, thermal, and fluorescence properties have also been studied. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.06.029