C6H4-1-(CH2PPh2(BH3))-3-CH2P(CHMe2)2(BH3)) | 745822-88-2

• 英文名称: C6H4-1-(CH2PPh2(BH3))-3-CH2P(CHMe2)2(BH3))
• CAS: 745822-88-2
• 化学式: C₂₆H₃₈B₂P₂
• 分子量: 434.157
• InChiKey: FRTZYEJXEBDCKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯二异丙基膦 在 n-butyllithium 作用下， 以 四氢呋喃 为溶剂， 生成 C6H4-1-(CH2PPh2(BH3))-3-CH2P(CHMe2)2(BH3))
  参考文献：
  名称：

  Synthesis of a new class of unsymmetrical PCP′ pincer ligands and their palladium (II) complexes: X-ray structure determination of PdCl{C6H3-2-CH2PPh2-6-CH2PBut2}

  摘要：

  The unsymmetrical PCPt pincer ligands {C6H4-l-CH2PPh2-3-CH2PBu2t} and {C6H4-l-CH2PPh2-3-CH2PPr2i} and the corresponding palladium complexes: PdCl{C6H3-2-CH2PPh2-6-CH2PBu2t} and PdCl{CH3-2-CH2PPh2-6-CHPPr2i} have been synthesized in good yields. The molecular structure of PdCl{C6H3-2-CH2PPh2-6-CH2Bu2t} was determined through a single crystal X-ray diffraction study. The palladium center was found to be located into a slightly distorted square planar environment in which the {C6H4-1-CH2Ph2-3-CH2Bu2t} ligand is coordinated as a tridentate, PCP pincer type chelate. The complex, PdCl{C6H3-2CH(2)PPh(2)-6-CH2PPr2i} catalyzes the Heck coupling of iodobenzene with styrene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.009