| 1228030-69-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• CAS: 1228030-69-0
• 化学式: C₂₂H₂₂N₄
• 分子量: 342.443
• InChiKey: HTYJVRYIZLQXLB-PEBXRYMYSA-N

反应信息

• 作为产物：
  描述：

  2-氨甲基吡啶 、 (1R,4S)-3-hydroxyimino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 反应 1.0h， 以43%的产率得到
  参考文献：
  名称：

  One-step and solvent-free synthesis of fused terpene-pyrazines

  摘要：

  Solvent-free condensation reactions were carried out by heating terpene-monooximes with an excess of amines. Employing camphor- and nopinone-derived monooximes, two classes of terpene-fused pyrazine derivatives were synthesized. Besides being solvent-free, the described one-step procedure can be directed towards terpene-fused imidazole or pyrazine derivatives. Whereas the reaction worked well with arylmethanamines bearing a (hetero)aromatic substituent at the alpha-carbon, alkylamines afforded only imino-oximes. A possible reaction path is presented.

  DOI：

  10.3998/ark.5550190.0011.226