| 1358911-12-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• CAS: 1358911-12-2
• 化学式: C₃₄H₃₄N₂
• 分子量: 470.657
• InChiKey: NXNSULQWJVGWRA-BMCIMDJKSA-N

反应信息

• 作为反应物：
  描述：

  以 氘代二甲亚砜 为溶剂， 生成
  参考文献：
  名称：

  N,N′-Disubstituted phenanthrene-9,10-diimines: synthesis and NMR spectroscopic study

  摘要：

  Novel aryl-aryl, alkyl-alkyl, aryl-alkyl N,N'-disubstituted phenanthrene-9,10-diimines were synthesized by condensation of 9,10-phenanthrenequinone with primary amines. The novel two-stage method of synthesis of disubstituted phenanthrene-9,10-diimines with identical or different aryl and alkyl sub-stituents at the nitrogen atom was established. The investigated compounds undergo slow Z-EIE-Z interconversion which was studied by NMR spectroscopy. Thermodynamic parameters of interconversion were obtained by variable temperature NMR spectroscopy. (C) 2011 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2011.12.028
• 作为产物：
  描述：

  N-(2,6-dimethylphenyl)-phenanthren-o-iminoquinone 、 2,6-二异丙基苯胺 在 四氯化钛 、 三乙烯二胺 作用下， 以 甲苯 为溶剂， 反应 8.5h， 生成 、
  参考文献：
  名称：

  Chromium complexes supported by phenanthrene-imine derivative ligands: synthesis, characterization and catalysis on isoprene cis-1,4 polymerization

  摘要：

  在 CH2Cl2 中，CrCl2(THF)2 与 N-芳基-9,10-亚氨基蒽醌反应生成单亚胺铬络合物 ArIPQCrCl2(THF)2（1，Ar = 2,6-Me2C6H3；2，Ar = 2,6-Et2C6H3；3，Ar = 2,6-iPr2C6H3）。1 和 3 的分子结构被揭示为单体，铬原子呈扭曲的八面体几何结构。CrCl2(THF)2 与 N,N-双（芳基亚氨基）菲配体的类似反应产生了二亚胺配合物 Ar1,Ar2BIPCrCl(μ-Cl)3Cr(THF)Ar1,Ar2BIP（4，Ar1 = Ar2 = 2,6-Me2C6H3；5，Ar1 = Ar2 = 2,6-Me2C6H3；6，Ar1 = Ar2 = 2,6-Me2C6H3）；5，Ar1 = Ar2 = 2,6-Et2C6H3；6，Ar1 = Ar2 = 2,6-iPr2C6H3；7，Ar1 = 2,6-Me2C6H3，Ar2 = 2,6-iPr2C6H3）。X 射线衍射分析表明，4、5 和 7 是氯桥二聚体，每个铬原子都呈扭曲的八面体几何形状。在 MAO 的活化作用下，所有这些配合物在异戊二烯聚合过程中都表现出良好的催化活性，生成的聚异戊二烯主要具有顺式-1,4 单元。

  DOI：

  10.1039/c2dt11365a