(S_S^*,2S^*)-3-phenylsulfinyl-2,4-tridecanediol | 118429-63-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (S_S^*,2S^*)-3-phenylsulfinyl-2,4-tridecanediol
• CAS: 118429-63-3
• 化学式: C₁₉H₃₂O₃S
• 分子量: 340.527
• InChiKey: VBTNUUBMDMSOLS-IGOTWKNGSA-N

物化性质

• 沸点：
  528.4±40.0 °C(Predicted)
• 密度：
  1.09±0.1 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  癸醛 、 (R,R_S)-1-phenylsulfinyl-2-propanol 在 正丁基锂 作用下， 生成 (S_S^*,2S^*)-3-phenylsulfinyl-2,4-tridecanediol
  参考文献：
  名称：

  Reactivities of Diastereoisomeric Carbanions in Dianions Generated from β-Hydroxysulfoxides

  摘要：

  Dianions generated from β-hydroxysulfoxides reacted with n-C8H17I, n-C9H19CHO, and D2O to give products in different threo/erythro ratios, but those ratios were found to be essentially same in the early stage. The configurational interconversion of the diastereoisomeric carbanions would play an important role.

  DOI：

  10.1246/cl.1988.977