1,3-bis(3,3,4,4,5,5,6,6,6-nonafluorohexyloxy)-2-propanol | 384828-83-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 1,3-bis(3,3,4,4,5,5,6,6,6-nonafluorohexyloxy)-2-propanol
• 英文别名: 1,3-Bis[(3,3,4,4,5,5,6,6,6-nonafluorohexyl)oxy]propan-2-ol；1,3-bis(3,3,4,4,5,5,6,6,6-nonafluorohexoxy)propan-2-ol
• CAS: 384828-83-5
• 化学式: C₁₅H₁₄F₁₈O₃
• 分子量: 584.246
• InChiKey: KFFIJCKFHFFBBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  36
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  1,1-bis(acryloyloxymethyl)ethyl isocyanate 、 1,3-bis(3,3,4,4,5,5,6,6,6-nonafluorohexyloxy)-2-propanol 在 stannous octoate 、 4-甲氧基苯酚 作用下， 反应 9.25h， 以200 g的产率得到
  参考文献：
  名称：

  FLUORINE-CONTAINING URETHANE (METH)ACRYLATE, CURABLE COMPOSITION, AND ANTIREFLECTIVE FILM

  摘要：

  本发明旨在提供一种尿素（甲基）丙烯酸酯，能够形成具有低反射和优异耐磨性的固化层，以及使用该尿素（甲基）丙烯酸酯制备的可固化组合物和防反射膜。特别地，提供了一种含氟尿素（甲基）丙烯酸酯，其由通式（I）表示，其氟原子含量范围为25至60质量％（其中，R1和R2各代表特定的氟化烷基，R3和R4各代表氢原子或甲基基团，A代表由结构式（A1）至（A4）任一表示的三价连接基团，X和Y各自独立地代表由结构式（a）至（c）任一表示的二价连接基团）[在结构式（c）中，R5代表具有1至6个碳原子的烷基基团]。

  公开号：

  US20160208131A1

文献信息

• Fluorine-containing urethane (meth)acrylate, curable composition, and antireflective film
  申请人：DIC Corporation

  公开号：US10000657B2

  公开（公告）日：2018-06-19

  It is an object of the present invention to provide a urethane (meth)acrylate that enables formation of a cured layer having a low reflectance and excellent excoriation resistance, a curable composition produced by using the same, and an antireflective film. In particular, there is provided a fluorine-containing urethane (meth)acrylate represented by General Formula (I) and having a fluorine atom content ranging from 25 to 60 mass % (where R1 and R2 each represent a specific fluorinated alkyl group, R3 and R4 each represent a hydrogen atom or a methyl group, A represents a trivalent linking group represented by any of Structural Formulae (A1) to (A4), and X and Y each independently represent a divalent linking group represented by any of Structural Formulae (a) to (c)) [in Structural Formula (c), R5 represents an alkyl group having 1 to 6 carbon atoms].

  本发明的目的是提供一种能够形成具有低反射率和优异耐辐照性的固化层的聚氨酯（甲基）丙烯酸酯、使用该聚氨酯（甲基）丙烯酸酯生产的可固化组合物以及防反射膜。其中，R1 和 R2 分别代表特定的氟化烷基，R3 和 R4 分别代表氢原子或甲基、A 代表结构式（A1）至（A4）中任一式所代表的三价连接基团，X 和 Y 各自独立地代表结构式（a）至（c）中任一式所代表的二价连接基团）[在结构式（c）中，R5 代表具有 1 至 6 个碳原子的烷基]。
• ORGANIC SEMICONDUCTOR INK COMPOSITION AND METHOD FOR FORMING ORGANIC SEMICONDUCTOR PATTERN USING THE SAME
  申请人：Koutake Masayoshi

  公开号：US20120100667A1

  公开（公告）日：2012-04-26

  Provided is an ink that is the most suitable for a method for forming an organic transistor by transferring a pattern using a liquid-repellent transfer substrate, for example, a microcontact printing method or a reverse printing method. Specifically, provided is an organic semiconductor ink composition which can provide a uniform ink coating film on a surface of a liquid-repellent transfer substrate and which can provide a dry ink film or a semi-dry ink film capable of being easily transferred from the transfer substrate to a transfer-receiving base material. Also provided is a method for forming an organic semiconductor pattern of an organic transistor, the method using the organic semiconductor ink composition. The organic semiconductor ink composition used for obtaining a desired pattern by transferring an ink layer formed on a liquid-repellent transfer substrate to a printing base material contains an organic semiconductor, an organic solvent, and a fluorine-based surfactant.