Butyl-phenyl-hydrogenphosphit | 876501-68-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Butyl-phenyl-hydrogenphosphit
• 英文别名: Butyl-phenyl-phosphit；Butyl phenyl hydrogen phosphite
• CAS: 876501-68-7
• 化学式: C₁₀H₁₅O₃P
• 分子量: 214.201
• InChiKey: YRBPWUVLGQCDHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Butyl-phenyl-hydrogenphosphit 在 potassium fluoride 、 磺酰氯 、 水 作用下， 以 四氯化碳 、 苯 为溶剂， 生成 Butyl-phenyl-fluor-phosphat
  参考文献：
  名称：

  Maklyaev,F.L. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3357 - 3360

  摘要：

  DOI：
• 作为产物：
  描述：

  苯氧基亚磷酰二氯 、 正丁醇 生成 Butyl-phenyl-hydrogenphosphit
  参考文献：
  名称：

  Maklyaev,F.L. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3357 - 3360

  摘要：

  DOI：

文献信息

• PHOSPHONO PARAFFINS
  申请人：THE BOEING COMPANY

  公开号：US20180195019A1

  公开（公告）日：2018-07-12

  Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I): wherein each instance of R 1 is independently —H wherein each instance of R 2 and R 3 is independently linear or branched C 1-20 alkyl, C 1-20 cycloalkyl, or aryl; the number of instances where R 1 is of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

  本文描述的方面通常涉及制备磷酸酯烷的方法，包括通过混合卤代烷，磷酸酯和碘化钠形成反应混合物。方法包括加热反应混合物以形成磷酸酯烷。本文所述的方面还涉及由公式（I）表示的磷酸酯烷： 其中，R1的每个实例独立地为-H，R2和R3的每个实例独立地为线性或支链的C1-20烷基，C1-20环烷基或芳基；R1在公式（I）中的实例数在大约2到大约8之间；n是介于4到22之间的整数。
• Verfahren zur Herstellung von m-Aminophenolen
  申请人：BASF Aktiengesellschaft

  公开号：EP0013382A1

  公开（公告）日：1980-07-23

  Verfahren zur Herstellung von m-Aminophenolen durch Umsetzung von Resorcin mit sekundären, cyclischen Aminen in Gegenwart von Phosphor-III -verbindungen in zwei Stufen unterschiedlicher Temperatur. Die nach dem Verfahren der Erfindung herstellbaren m-Aminophenole I sind wertvolle Zwischenprodukte für die Herstellung von Pflanzenschutzmitteln, von optischen Aufhellern, insbesondere von Amino-Cumarin -Derivaten, und von Farbstoffen, besonders der Xanthen-, Pyronin-, Rhodaminund Oxazin-Reihen.

  间氨基苯酚的制备工艺：间苯二酚与仲环胺在磷Ⅲ化合物存在下，在不同温度下分两步进行反应。 通过本发明的工艺可以制得的间氨基苯酚 I 是生产植物保护剂、光学增白剂（特别是氨基香豆素衍生物）和染料（特别是呫吨、吡喃、罗丹明和噁嗪系列）的重要中间体。
• 2,6-Di-tertiary butyl phenyl phosphites and synthetic resin compositions containing these phosphites
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0033395A2

  公开（公告）日：1981-08-12

  2,6-Di-tertiary butyl phenyl phosphites are provided having the structure: wherein: R is selected from the group consisting of hydrogen, methyl, ethyl, and (CH2)mCOOR, where R is selected from the group consisting of alkyl having from one up to about ten carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about twelve carbon atoms; and m is a number within the range from 0 to 5; R2 is selected from the group consisting of hydrogen, alkyl having from one to about twenty-two carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; the residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to three hydroxyl groups; and the residue of a polyphenol having from six to about eighteeen carbon atoms and from two to about ten phenolic hydroxyl groups; R3 is selected from the group consisting of hydrogen and P(OR2)2; Z is the bivalent or trivalent residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to three hydroxyl groups; or of a polyphenol having from six to about eighteen carbon atoms and from two to about ten phenolic hydroxyl groups; n, is 0 or 1; and n2 is a number from 1 to 5; as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of an organic phosphite of this class.

  2,6-二叔丁基苯基亚磷酸酯具有以下结构： 其中 R选自由氢、甲基、乙基和(CH2)mCOOR组成的组，其中R选自由具有1至约10个碳原子的烷基、具有3至约12个碳原子的环烷基、具有6至约12个碳原子的烷芳基和芳基组成的组，m是0至5范围内的数字； R2 选自由氢、具有 1 至约 22 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的烷芳基和芳基、具有 2 至约 18 个碳原子和 2 至 3 个羟基的多元醇残基、具有 6 至约 8 个碳原子和 2 至约 10 个酚羟基的多元酚残基组成的组； R3 选自氢和 P(OR2)2 组成的组； Z 是二价或三价多元醇的残基，该多元醇具有 2 至约 18 个碳原子和 2 至 3 个羟基；或具有 6 至约 18 个碳原子和 2 至约 10 个酚羟基的多元酚的残基； n 是 0 或 1；以及 n2 是 1 至 5 的数字；以及合成树脂组合物，由于含有该类有机亚磷酸酯，其耐热和/或耐光变质的性能得到增强。
• Polyolefin compositions
  申请人：UNION CARBIDE CANADA LIMITED

  公开号：EP0067550A1

  公开（公告）日：1982-12-22

  There is disclosed a film forming polyolefin composition having improved melt fracture characteristics which comprises a high pressure polymer of an alpha olefin together with from 0.0001 to 3.0 PPHR of certain organo-phosphorous compounds.

  本发明公开了一种成膜聚烯烃组合物，它具有更好的熔融断裂特性，该组合物由 α 烯烃高压聚合物和 0.0001 至 3.0 PPHR 的某些有机磷化合物组成。
• A rotational moulding process using polyethylene compositions
  申请人：Du Pont Canada Inc.

  公开号：EP0087210A1

  公开（公告）日：1983-08-31

  A composition particularly adapted for use in a rotational moulding process is disclosed. The composition comprises polyethylene having a density of 0.920 - 0.970 g/cm3 and a melt index of 10-35 dg/min., 0.3 1.3% by weight of a bis(tert. alkyl peroxyalkyl) benzene, 0.2 - 1.5% by weight of a co-curing agent selected from triallyl cyanurate, triallyl isocyanurate and 1,2-polybutadiene, 0.01 - 0.05% by weight of a hindered phenolic antioxidant and 0.01 - 0.2% by weight of a secondary antioxidant. The preferred secondary antioxidant is tris di(tert.-butyl phenyl) phosphite. The composition may be used in for example, the moulding of tanks, barrels, containers and the like.

  本发明公开了一种特别适用于滚塑工艺的组合物。该组合物包括密度为 0.920 - 0.970 g/cm3 和熔融指数为 10-35 dg/min 的聚乙烯、0.3-1.3%（按重量计）的双(叔烷基过氧烷基)苯，0.2-1.5%（按重量计）的选自氰尿酸三烯丙基酯、异氰尿酸三烯丙基酯和 1,2-聚丁二烯的辅助固化剂，0.01-0.05%（按重量计）的受阻酚类抗氧化剂和 0.01-0.2%（按重量计）的二级抗氧化剂。首选的二级抗氧化剂是亚磷酸三二（叔丁基苯基）酯。该组合物可用于例如罐、桶、容器等的成型。