[Cu(2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)(-2H))] | 1178554-89-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)(-2H))]
• CAS: 1178554-89-6
• 化学式: C₃₆H₄₆CuN₂O₄
• 分子量: 634.318
• InChiKey: LLBCJLWQWHRMDR-JGZZKDFUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(pentamethylcyclopentadienyl)zirconium dimethyl 、 [Cu(2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)(-2H))] 、 甲苯 以 甲苯 为溶剂， 以60%的产率得到Cu(2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)(-4H))Zr(C5Me5)2*toluene
  参考文献：
  名称：

  Monometallic and heterobimetallic complexes derived from salen-type ligands

  摘要：

  Mononuclear and heterodinuclear complexes of the salen-type ligand H2LH2 [H2LH2 = 2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)] were prepared, whereof [{Mn(CH3OH)(2)}LH2]Cl, [ML(ZrCp2*)] (M = Ni, Cu, CrCl(py); py = pyridine, Cp* = pentamethylcyclopentadienyl) were characterized by X-ray analysis. Additionally, cyclic voltammetric investigations were performed to ascertain the influence of the second transition metal complex fragment [ZrCp2*](2+) on the metallo salen ligand. Moreover, the complexes were tested in the catalytic epoxidation of styrene. Although the complexes are quite sensitive towards oxidants, monometallic complex [{Mn(CH3OH)(2)}LH2]Cl exhibited a conversion of 70.6% with styrene oxide selectivity of 88% over 1 h at room temperature. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.017
• 作为产物：
  描述：

  2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol) 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 以77%的产率得到[Cu(2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)(-2H))]
  参考文献：
  名称：

  Monometallic and heterobimetallic complexes derived from salen-type ligands

  摘要：

  Mononuclear and heterodinuclear complexes of the salen-type ligand H2LH2 [H2LH2 = 2,2'-[1,2-dihydroxybenzene-4,5-diylbis(nitrilomethylidine)]bis(3,5-di-tert-butylphenol)] were prepared, whereof [{Mn(CH3OH)(2)}LH2]Cl, [ML(ZrCp2*)] (M = Ni, Cu, CrCl(py); py = pyridine, Cp* = pentamethylcyclopentadienyl) were characterized by X-ray analysis. Additionally, cyclic voltammetric investigations were performed to ascertain the influence of the second transition metal complex fragment [ZrCp2*](2+) on the metallo salen ligand. Moreover, the complexes were tested in the catalytic epoxidation of styrene. Although the complexes are quite sensitive towards oxidants, monometallic complex [{Mn(CH3OH)(2)}LH2]Cl exhibited a conversion of 70.6% with styrene oxide selectivity of 88% over 1 h at room temperature. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.017