4-丙基苯甲酸-4-氰基-3,5-二氟苯酯 | 193275-43-3

• 物质功能分类: 有机原料 - 醇、酚、酚醇类化合物及衍生物 - 酚及其卤化、磺化、硝化或亚硝化衍生物
• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 中文名称: 4-丙基苯甲酸-4-氰基-3,5-二氟苯酯
• 英文名称: 4-Cyano-3,5-difluorophenyl 4-propyl-benzoate
• 英文别名: (4-cyano-3,5-difluorophenyl) 4-propylbenzoate
• CAS: 193275-43-3
• 化学式: C₁₇H₁₃F₂NO₂
• 分子量: 301.29
• InChiKey: HEFCYPVDRJVTRA-UHFFFAOYSA-N

物化性质

• 沸点：
  416.7±45.0 °C(Predicted)
• 密度：
  1.26±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• METHOD FOR OBTAINING A MATERIAL COMPRISING A LIQUID CRYSTAL MIX WITH A STABILIZED BLUE PHASE AND OPTICAL ARTICLE COMPRISING THIS MATERIAL
  申请人：ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE)

  公开号：EP3115436A1

  公开（公告）日：2017-01-11

  The invention relates to a method for obtaining a material (10) comprising mesogenic compounds (101) forming a liquid crystal mix with a stabilized blue phase (100), comprising the following steps: a) preparing a chemical composition comprising a mesogenic system and a chemical photo-initiator system, the mesogenic system including - said mesogenic compounds forming the liquid crystal mix, - a chiral dopant adapted to induce said blue phase, and - a monomer mix comprising monomers adapted to polymerize, and the chemical photo-initiator system being adapted to trigger the polymerization of said monomers when illuminated by a light beam of visible wavelength; b) getting said liquid crystal mix to form said blue phase; c) after getting said liquid crystal mix into said blue phase, illuminating the chemical composition obtained in step a) with a light beam of visible wavelength in order to trigger the polymerization of said monomers; d) obtaining said material comprising said liquid crystal mix in the blue phase stabilized by the polymerized monomers.

  本发明涉及一种获得材料（10）的方法，该材料由中间体化合物（101）组成，与稳定蓝相（100）形成液晶混合物，包括以下步骤： a) 制备一种化学组合物，该化学组合物包括介源体系和化学光引发剂体系，介源体系包括 - 形成液晶混合物的中生化合物、 - 用于诱导所述蓝相的手性掺杂剂，以及 - 由适于聚合的单体组成的单体混合物、 化学光引发剂系统可在可见光光束照射下引发所述单体聚合； b) 让所述液晶混合物形成所述蓝相； c) 在所述液晶混合物进入所述蓝相后，用可见光光束照射在步骤 a) 中获得的化学成分，以引发所述单体的聚合； d) 在蓝色相中获得由聚合单体稳定的液晶混合物组成的材料。
• Method for obtaining a material comprising a liquid crystal mix with a stabilized blue phase and optical article comprising this material
  申请人：Essilor International

  公开号：US10920145B2

  公开（公告）日：2021-02-16

  A method for obtaining a material containing mesogenic compounds forming a liquid crystal mix with a stabilized blue phase. The method includes the steps of a) inducing the liquid crystal mix, contained in a chemical composition, to form the blue phase, then b) illuminating the chemical composition with a light beam of visible wavelength in order to trigger the polymerization of monomers contained in the chemical composition, to obtain the material comprising the liquid crystal mix in the blue phase stabilized by the polymerized monomers. The chemical composition contains a mesogenic system and a chemical photo-initiator system adapted to trigger the polymerization of the monomers when illuminated by the light beam of visible wavelength, in which the mesogenic system includes the mesogenic compounds forming the liquid crystal mix, a chiral dopant adapted to induce the blue phase, and a monomer mix comprising the monomers adapted to polymerize.

  一种获得含有中生化合物的材料的方法，该材料可形成具有稳定蓝相的液晶混合物。该方法包括以下步骤：a) 诱导化学组合物中的液晶混合物形成蓝相，然后 b) 用可见光波长的光束照射化学组合物，以引发化学组合物中所含单体的聚合，从而获得由聚合单体稳定的蓝相液晶混合物组成的材料。该化学组合物包含一个中间体系统和一个化学光引发剂系统，当可见光光束照射时，化学光引发剂系统可引发单体聚合，其中中间体系统包括形成液晶混合物的中间体化合物、一个可引发蓝相的手性掺杂剂和一个包含可聚合单体的单体混合物。
• LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Ishitani Tetsuji

  公开号：US20120132855A1

  公开（公告）日：2012-05-31

  To provide a liquid crystal composition exhibiting a blue phase, which enables higher contrast, and a liquid crystal display device including the liquid crystal composition. The liquid crystal composition contains a chiral agent and liquid crystal containing a compound having three electron-withdrawing groups as end groups of a structure where a plurality of rings including at least one aromatic ring is linked to each other directly or with a linking group laid therebetween. The peak of the diffracted wavelength on the longest wavelength side in the reflectance spectrum of the liquid crystal composition is less than or equal to 450 nm, preferably less than or equal to 420 nm. Further, a liquid crystal display device can be provided using the liquid crystal composition.
• METHOD FOR MANUFACTURING LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Kubota Daisuke

  公开号：US20130020023A1

  公开（公告）日：2013-01-24

  A liquid crystal display device which includes a liquid crystal composition exhibiting a blue phase and has high reliability is provided. In a manufacturing method of a liquid crystal display device which includes a liquid crystal composition exhibiting a blue phase, the liquid crystal composition including nematic liquid crystal, a chiral agent, a polymerizable monomer, and a photopolymerization initiator which absorbs light with a peak wavelength that is different from a peak wavelength of light absorbed by the nematic liquid crystal is used. The liquid crystal composition is capable of exhibiting a blue phase and is irradiated with light absorbed by the photopolymerization initiator so that the liquid crystal composition is polymerized.
• LIQUID CRYSTAL COMPOSITION, LIQUID CRYSTAL ELEMENT, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：TAMURA Tomohiro

  公开号：US20130009094A1

  公开（公告）日：2013-01-10

  A liquid crystal composition including a dioxolane compound represented by the general formula (G1) as a chiral agent is provided. In the general formula (G1), R 1 and R 2 individually represent any of hydrogen, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 12 carbon atoms, and an alkyl group having 1 to 20 carbon atoms and having a phenyl group as a substituent; R 1 and R 2 may be bonded to each other to form a ring; R 3 and R 4 individually represent any of hydrogen, an alkyl group having 1 to 6 carbon atoms, and a cycloalkyl group; and R 5 to R 40 individually represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, and an aryl group having 6 to 12 carbon atoms.