N,N'-[1,3-phenylenebis(methylene)]bis-(2,3-dihydroxybenzamide) | 188746-14-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-[1,3-phenylenebis(methylene)]bis-(2,3-dihydroxybenzamide)
• 英文别名: α,α-bis(2,3-dihydroxybenzoylamino)-m-xylene；N-[[3-[[(2,3-dihydroxybenzoyl)amino]methyl]phenyl]methyl]-2,3-dihydroxybenzamide
• CAS: 188746-14-7
• 化学式: C₂₂H₂₀N₂O₆
• 分子量: 408.411
• InChiKey: WOPCEHKUTOICQM-UHFFFAOYSA-N

物化性质

• 沸点：
  706.7±60.0 °C(Predicted)
• 密度：
  1.431±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  139
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-[1,3-phenylenebis(methylene)]bis-(2,3-dihydroxybenzamide) 在 硫酸 作用下， 以72%的产率得到
  参考文献：
  名称：

  Sequestering agent for uranyl chelation: a new family of CAMS ligands

  摘要：

  The synthesis of new dipodal bis-sulfocatecholamide uranophiles is presented. Their binding abilities for uranyl cation were determined by UV spectro photometry in aqueous media under various pH conditions and further studied by H-1 NMR analysis of the resonance signal of both aromatic protons of the sulfocatecholamide groups. The results showed that the efficiency of these hydrosoluble chelating agents depends on the nature of the spacers. Each ligand shows a more or less pronounced affinity for uranium. The best receptor is the ligand CYCAMS 5d obtained as a mixture of cis/trans isomers, which achieves the best compromise between rigidity and steric hindrance. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.05.021
• 作为产物：
  描述：

  N,N'-[1,3-phenylenebis(methylene)]bis-(2,3-dimethoxybenzamide) 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以90%的产率得到N,N'-[1,3-phenylenebis(methylene)]bis-(2,3-dihydroxybenzamide)
  参考文献：
  名称：

  Sequestering agent for uranyl chelation: a new family of CAMS ligands

  摘要：

  The synthesis of new dipodal bis-sulfocatecholamide uranophiles is presented. Their binding abilities for uranyl cation were determined by UV spectro photometry in aqueous media under various pH conditions and further studied by H-1 NMR analysis of the resonance signal of both aromatic protons of the sulfocatecholamide groups. The results showed that the efficiency of these hydrosoluble chelating agents depends on the nature of the spacers. Each ligand shows a more or less pronounced affinity for uranium. The best receptor is the ligand CYCAMS 5d obtained as a mixture of cis/trans isomers, which achieves the best compromise between rigidity and steric hindrance. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.05.021

文献信息

• Synthesis, characterisation, and solution behaviour of two dioxomolybdenum(VI) complexes of a bis(catecholamide) siderophore analogue
  作者：Anne-Kathrin Duhme

  DOI：10.1039/a607163e

  日期：——

  The bis(catecholamide) α,α′-bis(2,3-dihydroxybenzoylamino)-m-xylene (H 4 L 3 ) has been synthesized and characterised. It is an analogue of the naturally occurring siderophore azotochelin and structurally related to an approved enterobactin model. Two dioxomolybdenum(VI) complexes of it have been synthesized, namely a di- and a mono-nuclear one. Variable-temperature proton NMR studies of the initially obtained dinuclear compound revealed that three kinetic processes are operative in Me 2 SO solution: geometrical isomerisation at lower temperatures, and inversion of configuration concomitant with dissociation into the monomer at higher temperatures. In contrast, the mononuclear complex obtained in this way isomerises and inverts almost simultaneously at 343–353 K. The crystal structure of Na 2 [MoO 2 L 3 ] confirmed the mononuclear nature of the complex and revealed that the cis, cis, cis geometrical isomer is adopted in the solid state.

  双（儿茶酚胺）α，α′-双（2，3-二羟基苯甲酰氨基）-间二甲苯（H4L3）已合成并鉴定。它是一种天然存在的铁载体氮化铁的类似物，在结构上与一种已批准的肠杆菌素模型有关。已合成了两种二氧代钼（VI）复合物，即二核和单核。对最初获得的双核化合物进行可变温度质子核磁共振（NMR）研究显示，在Me2SO溶液中有三种动力学过程：在较低温度下发生几何异构化，在较高温度下发生构象反转并分解为单体。与此相反
• [EN] NOVEL FORMO-PHENOLIC RESINS, PROCESS FOR THE PREPARATION THEREOF, AND USE OF SAME IN THE EXTRACTION OF URANIUM FROM WATER<br/>[FR] NOUVELLES RESINES FORMO-PHENOLIQUES, LEUR PROCEDE DE PREPARATION, ET LEUR UTILISATION DANS L'EXTRACTION DE L'URANIUM DE L'EAU
  申请人：[fr]CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

  公开号：WO2022090242A1

  公开（公告）日：2022-05-05

  La présente invention a pour objet des résines formo-phénoliques, leur procédé de préparation, ainsi que leur utilisation dans l'extraction de l'uranium d'un échantillon aqueux. La présente Invention a également pour objet des nouvelles résines formo-phénoliques.