1,1,1,3,3,3-hexafluoro-2,2-bis(4-iodophenyl)propane | 55100-57-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1,1,3,3,3-hexafluoro-2,2-bis(4-iodophenyl)propane
• 英文别名: 2,2-bis(4-iodophenyl)hexafluoropropane；Benzene, 1,1'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[4-iodo-；1-[1,1,1,3,3,3-hexafluoro-2-(4-iodophenyl)propan-2-yl]-4-iodobenzene
• CAS: 55100-57-7
• 化学式: C₁₅H₈F₆I₂
• 分子量: 556.028
• InChiKey: UUIRFPVOWVRSRS-UHFFFAOYSA-N

物化性质

• 沸点：
  358.4±42.0 °C(Predicted)
• 密度：
  1.988±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,1,1,3,3,3-hexafluoro-2,2-bis(4-iodophenyl)propane 、 3,5-双三氟甲基苯乙炔 在 Pd-based catalyst 作用下， 以81%的产率得到5,5'-(((perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(ethyne-2,1-diyl))bis(1,3-bis(trifluoromethyl)benzene)
  参考文献：
  名称：

  Novel fluorine-containing bis(tetraarylcyclopentadienones)

  摘要：

  DOI：

  10.1134/s0012500809110068
• 作为产物：
  描述：

  2,2-bis(4-bromophenyl)hexafluoropropane 、 sodium hydrogensulfite 在 正丁基锂 、 碘 作用下， 以 乙醚 、 正己烷 、 水 为溶剂， 生成 1,1,1,3,3,3-hexafluoro-2,2-bis(4-iodophenyl)propane
  参考文献：
  名称：

  Process for making bis(halophenyl)hexafluoropropanes

  摘要：

  本发明揭示了一种制备在苯环上含有卤素取代基的六氟丙烷二苯衍生物的新工艺，以及由此制备的新的卤素取代的六氟丙烷二苯衍生物。本发明的新化合物可用作高温聚合物体系的合成中间体。

  公开号：

  US04503254A1

文献信息

• Bis(halophenyl)hexafluoropropanes and process for making the same
  申请人：Hughes Aircraft Company

  公开号：EP0092310A1

  公开（公告）日：1983-10-26

  (57) A new process for preparing diphenyl derivatives of hexafluoropropane containing halogen substituents on the phenyl rings and new halogen-substituted diphenyl derivatives of hexafluoropropane prepared thereby are disclosed. The new compounds of this invention are useful as intermediates for the synthesis of high temperature polymer systems.

  (57) 本发明公开了一种制备苯环上含有卤素取代基的六氟丙烷二苯基衍生物的新工艺，以及由此制备的六氟丙烷卤素取代二苯基新衍生物。本发明的新化合物可用作合成高温聚合物体系的中间体。
• Preparation of poly(benz(ox, imid, thi)azole) polymers
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0522469A2

  公开（公告）日：1993-01-13

  A method for the preparation of poly(benzoxazole)s, poly(benzimidazole)s, and poly(benzthiazole)s. In the presence of solvent and catalyst, reacting carbon monoxide, an aromatic halide reactant having the general formula X¹-Ar¹-Z¹ and an aromatic amine reactant having the general formula Z²-Ar²-M¹, wherein X¹ and Z¹ are non-ortho, Z² and M¹ are non-ortho, one of Z¹ and Z² is X² and the other one is M², -Ar¹- and -Ar²- are each independently selected from the group consisting of aromatic and hetero-aromatic moieties having a total of ring carbons and heteroatoms of from 6 to 20, X¹ and X² are each independently selected from the group consisting of -I and -Br, and M¹ and M² are each independently selected from moieties having an -NH₂ radical and, ortho to the -NH₂ radical, a radical selected from the group consisting of -NH₂, -OH, and -SH.

  一种制备聚（苯并恶唑）、聚（苯并咪唑）和聚（苯并噻唑）的方法。在溶剂和催化剂存在下，使一氧化碳、通式为 X¹-Ar¹-Z¹ 的芳族卤化物反应物和通式为 Z²-Ar²-M¹ 的芳族胺反应物反应，其中 X¹ 和 Z¹ 为非正交，Z² 和 M¹ 为非正交，Z¹ 和 Z² 中的一个为 X²，另一个为 M²、-Ar¹-和-Ar²-各自独立地选自由环碳原子和杂原子总数为 6 至 20 的芳香族和杂芳香族分子组成的组，X¹和 X² 各自独立地选自由-I 和-Br 组成的组，M¹和 M² 各自独立地选自由具有-NH₂基的分子以及与-NH₂基正交的选自由-NH₂、-OH 和-SH 组成的组的基。
• Diyne-containing (co) polymer, processes for producing the same, and cured film
  申请人：JSR Corporation

  公开号：EP1099719A1

  公开（公告）日：2001-05-16

  A diyne-containing (co)polymer which is soluble in organic solvents, has excellent processability, and gives a cured coating film excellent in heat resistance, solvent resistance, low-dielectric characteristics, and mechanical strength; processes for producing the same; and a cured film. The diyne-containing (co)polymer contains at least 10 mol% repeating units represented by the following formula (1) and has a weight-average molecular weight of from 500 to 1,000,000: wherein Y represents a specific bivalent organic group; Ar represents a bivalent organic group; and n represents 0 or 1.

  一种可溶于有机溶剂、加工性能优异、固化涂膜的耐热性、耐溶剂性、低介电特性和机械强度优异的含二炔（共）聚合物；生产该聚合物的工艺；以及固化涂膜。 含二炔（共）聚合物含有至少 10 摩尔%的重复单元，由下式（1）表示，其重量平均分子量为 500 至 1,000,000 之间： 其中 Y 代表特定的二价有机基团；Ar 代表二价有机基团；n 代表 0 或 1。
• Monomer containing electron-withdrawing group and electron-donative group, and copolymer and proton-conductive membrane comprising same
  申请人：JSR Corporation

  公开号：EP1245554A1

  公开（公告）日：2002-10-02

  A monomer containing an electron-withdrawing group and an electron-donative group which can be easily controlled in the upper limit of the amount of a sulfonic acid , which impairs the mechanical properties of a copolymer, and can provide a sulfonated polymer that forms a proton-conductive membrane having a high proton conductivity over a wide temperature range, an excellent mechanical strength and an excellent proton conductivity and showing inhibited swelling in hot water and an aqueous solution of methanol, and a copolymer obtained from the monomer. A monomer containing an electron-withdrawing group and an electron-donative group represented by the following general formula (1) : wherein Y represents a iodine atom, chlorine atom or bromine atom; X represents an electron-withdrawing group; B represents an electron-donative group; and Z represents an aryl group having a specific structure or a monovalent condensed ring hydrocarbon group such as naphthyl group.

  一种含有一个抽电子基团和一个负电子基团的单体，该单体可以很容易地控制磺酸的用量上限，而磺酸会损害共聚物的机械性能，并可以提供一种磺化聚合物，该聚合物可以在很宽的温度范围内形成具有高质子传导性、优异的机械强度和优异的质子传导性的质子传导膜，并在热水和甲醇水溶液中表现出抑制溶胀的特性，以及由该单体得到的共聚物。一种单体，含有由下式通式（1）代表的一个电子吸收基团和一个电子疏导基团： 其中 Y 代表碘原子、氯原子或溴原子；X 代表抽电子基团；B 代表弃电子基团；Z 代表具有特定结构的芳基或一价缩合环烃基团，如萘基。
• Anion exchange resin, electrolyte membrane, binder for forming electrode catalyst layer, fuel cell electrode catalyst layer and fuel cell
  申请人：University Of Yamanashi

  公开号：US11173484B2

  公开（公告）日：2021-11-16

  Provided are an anion exchange resin being capable of producing an electrolyte membrane, a binder for forming an electrode catalyst layer and a battery electrode catalyst layer, which have improved electrical properties and chemical properties. For example, used is an anion exchange resin which has a hydrophobic unit being composed of bisphenol AF residues repeated via carbon-carbon bond and a hydrophilic unit being composed of hydrophilic groups repeated via carbon-carbon bond, in which the hydrophilic group is formed by connecting an anion exchange group to a fluorene backbone via a divalent saturated hydrocarbon group, and in which the hydrophobic unit and the hydrophilic unit are connected via carbon-carbon bond.

  本发明提供了一种阴离子交换树脂，可用于生产电解质膜、形成电极催化剂层的粘结剂和电池电极催化剂层，其电气性能和化学性能均有所改善。例如，所使用的阴离子交换树脂具有通过碳-碳键重复的双酚 AF 残基组成的疏水单元和通过碳-碳键重复的亲水基团组成的亲水单元，其中亲水基团是通过二价饱和烃基将阴离子交换基团连接到芴骨架上形成的，并且疏水单元和亲水单元通过碳-碳键连接。