3a-methyl-3,3,4,4,9,9-hexaphenylhexahydro-1H-3al5-3a,6a-propanopentalene | 123224-14-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3a-methyl-3,3,4,4,9,9-hexaphenylhexahydro-1H-3al5-3a,6a-propanopentalene
• CAS: 123224-14-6
• 化学式: C₄₂H₄₃NP₃Pt
• 分子量: 849.811
• InChiKey: KHHBAZGQSJPKJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 氯化二乙基磷 、 四苯硼钠 在 H₂O or alcohol 作用下， 以 四氢呋喃 、 苯 为溶剂， 生成 3a-methyl-3,3,4,4,9,9-hexaphenylhexahydro-1H-3al5-3a,6a-propanopentalene
  参考文献：
  名称：

  Dechlorination of ClPEt2 by (np3)Pt(PPh3) (np3N(CH2CH2PPh2)3): synthesis and characterization of [(np3)Pt(PEt2)](BPh4) and [(np3)Pt(PHEt2)](BPh4)2

  摘要：

  The platinum(0) complex (np3)Pt(PPh3) (np3 = N(CH2CH2PPh2)3), undergoes oxidative addition by ClPEt2, in the presence of NaBPh4, to yield the five-coordinate terminal phosphide [(np3)Pt(PEt2)](BPh4). When the solvated compound (np3)Pt(PPh3).0.4CH3CH2CH2CH2OH is used as starting material, [(np3)Pt(PHEt2)](BPh4)2 is formed by reaction of the phosphide with HCl released by alcoholysis of ClPEt2. The related complex [(pp3)Pt(PEt2)](BPh4) (pp3 = {P(CH2CH2PPh2)3}) has been prepared by deprotonation of [(pp3)Pt(PHEt2)](BPh4)2, for comparison purposes. The complexes have been characterized by elemental analyses, conductibility measurements and H-1 and P-31 NMR spectra. The X-ray structural analysis of [(np3)Pt(PHEt2)](BPh4)2 has been carried out.

  DOI：

  10.1016/s0020-1693(00)80395-3