bis(N,N-dimethyldithiocarbamato)iodobismuth | 367256-20-0

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: bis(N,N-dimethyldithiocarbamato)iodobismuth
• CAS: 367256-20-0
• 化学式: C₆H₁₂BiIN₂S₄
• 分子量: 576.324
• InChiKey: ZXDMNZRBTDOUAE-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -2.62
• 重原子数：
  14.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  氢化铋 、 福美双 、 碘 以 甲苯 为溶剂， 以85%的产率得到bis(N,N-dimethyldithiocarbamato)iodobismuth
  参考文献：
  名称：

  COORDINATION COMPOUNDS OF TIN AND BISMUTH. COMPLEXES OF TIN(IV) AND BISMUTH(III) WITH N,N-DIALKYLDITHIOCARBAMATES

  摘要：

  Tin and bismuth metals react with N,N,N,N'-tetraethylthiuramdisulfide, [Et2NC(S)S](2), and N,N,N',N'-tetramcthylthiuramdisulfide, [Mt(2)NC(S)S](2), in refluxing toluene to give the compounds Sn(S2CNR2)(4) (R=Et, Me) in high yield. Under similar conditions bismuth gives Bi(S2CNR2)(3). The reaction of metallic tin with a mixture of iodine and [R2NC(S)S](2) gives the compounds SnI(S2CNR2)(3) and SnI2(S2CNR2)(2). Similarly, with mixtures of [R2NC(S)S](2) and I-2, bismuth yields BiI(S2CNR2)(2) and BiI2(S2CNR2). Adducts of Bi(S2CNR2)(3) with 1,10-phenanthroline and 2.2'-bipyridyl were also prepared. The compounds and adducts were characterized by microanalyses, infrared, UV/Visible spectroscopy and conductivity measurements.

  DOI：

  10.1081/sim-100104783