cis-bis(pentafluorophenyl)(2-[(1,2-η-phenyl)phenylmethyl]pyridine-κN)platinum(II) | 171975-59-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-bis(pentafluorophenyl)(2-[(1,2-η-phenyl)phenylmethyl]pyridine-κN)platinum(II)
• 英文别名: 2-benzhydrylpyridine;1,2,3,4,5-pentafluorobenzene-6-ide;platinum(2+)
• CAS: 171975-59-0
• 化学式: C₃₀H₁₅F₁₀NPt
• 分子量: 774.52
• InChiKey: NADQSZFGAQDRMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-bis(pentafluorophenyl)(2-[(1,2-η-phenyl)phenylmethyl]pyridine-κN)platinum(II) 在 CO 作用下， 以 二氯甲烷 为溶剂， 以88%的产率得到cis-carbonyl[2-(diphenylmethyl)pyridine]bis(pentafluorophenyl)platinum(II)
  参考文献：
  名称：

  Pentafluorophenylplatinum complexes containing η¹- or η²-aryl–Pt interactions. Crystal structure of cis-[Pt(C₆F₅)₂-({NC₅H₄[CH(η²-Ph)Ph]-2}-κN)]·0.5C₆H₅Me

  摘要：

  The reaction of cis-[Pt(C6F5)(2)(thf)(2)] 1 (thf=tetrahydrofuran) with a 1:1 molar ratio of 2-(diphenylmethyl) pyridine or tribenzylamine in CH2Cl2 resulted in displacement of the thf molecules and formation of cis-[Pt(C6F5)(2){NC5H4(CHPh(2))-2}] 2 and cis-[Pt(C6F5)(2){N(CH(2)Ph)(3)}] 3 respectively. The solid-state structure of 2 has been established by X-ray diffraction methods and reveals the existence of a eta(2)-phenyl-Pt interaction which is maintained in solution (NMR). Crystal data for 2.0.5C(6)H(5)Me: C33.5H19F10NPt, triclinic, space group P ($) over bar 1, a=11.653(4), b=12.345(3), c=12.499(4) Angstrom, alpha=1:16.91(2), beta=104.33(2). gamma=103.41(2)degrees. Z=2, R=0.038 for 2791 unique 'observed' absorption-corrected reflections collected at 233 K. Complexes 2 and 3 reacted with CO yielding cis-[Pt(C6F5)(2){NC5H4(CHPh(2))-2}(CO)] and cis-[Pt(C6F5)(2){N (CH(2)Ph)(3)}(CO)] respectively.

  DOI：

  10.1039/dt9950002949
• 作为产物：
  描述：

  二苯基-2-吡啶基甲烷 、 cis-[(pentafluorophenyl)2 (tetrahydrofurane)2 platinum(II)] 以 二氯甲烷 为溶剂， 以83%的产率得到cis-bis(pentafluorophenyl)(2-[(1,2-η-phenyl)phenylmethyl]pyridine-κN)platinum(II)
  参考文献：
  名称：

  Pentafluorophenylplatinum complexes containing η¹- or η²-aryl–Pt interactions. Crystal structure of cis-[Pt(C₆F₅)₂-({NC₅H₄[CH(η²-Ph)Ph]-2}-κN)]·0.5C₆H₅Me

  摘要：

  The reaction of cis-[Pt(C6F5)(2)(thf)(2)] 1 (thf=tetrahydrofuran) with a 1:1 molar ratio of 2-(diphenylmethyl) pyridine or tribenzylamine in CH2Cl2 resulted in displacement of the thf molecules and formation of cis-[Pt(C6F5)(2){NC5H4(CHPh(2))-2}] 2 and cis-[Pt(C6F5)(2){N(CH(2)Ph)(3)}] 3 respectively. The solid-state structure of 2 has been established by X-ray diffraction methods and reveals the existence of a eta(2)-phenyl-Pt interaction which is maintained in solution (NMR). Crystal data for 2.0.5C(6)H(5)Me: C33.5H19F10NPt, triclinic, space group P ($) over bar 1, a=11.653(4), b=12.345(3), c=12.499(4) Angstrom, alpha=1:16.91(2), beta=104.33(2). gamma=103.41(2)degrees. Z=2, R=0.038 for 2791 unique 'observed' absorption-corrected reflections collected at 233 K. Complexes 2 and 3 reacted with CO yielding cis-[Pt(C6F5)(2){NC5H4(CHPh(2))-2}(CO)] and cis-[Pt(C6F5)(2){N (CH(2)Ph)(3)}(CO)] respectively.

  DOI：

  10.1039/dt9950002949