RuCl(PPh3)(η(4)-Ph2C(OH)CH=C-2,6-(PPh2CH2)2C6H3) | 194427-00-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: RuCl(PPh3)(η(4)-Ph2C(OH)CH=C-2,6-(PPh2CH2)2C6H3)
• 英文别名: 3-[2,6-bis(diphenylphosphanylmethyl)phenyl]-1,1-diphenylprop-2-en-1-ol;chlororuthenium(1+);triphenylphosphane
• CAS: 194427-00-4
• 化学式: C₆₅H₅₄ClOP₃Ru
• 分子量: 1080.59
• InChiKey: WFMDBJQMZCGMPR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [1,3-(Ph2PCH2)2C6H3-2-Ru(Cl)PPh3] 、 1,1-二苯基-2-丙炔-1-醇 以 二氯甲烷 为溶剂， 以89%的产率得到RuCl(PPh3)(η(4)-Ph2C(OH)CH=C-2,6-(PPh2CH2)2C6H3)
  参考文献：
  名称：

  Coupling Reactions of Terminal Acetylenes with Ruthenium Complexes Containing the Ortho-Metalated Ligand 2,6-(PPh₂CH₂)₂C₆H₃

  摘要：

  Reactions of RuCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)(2)C6H3) with PhC equivalent to CH and HC equivalent to CC-(OH)Ph-2 gave the unusual coupling products RuCl(PPh3)(eta(4)-PhCH=C-2, 6-(PPh2CH2)(2)C6H3) and RuCl(PPh3)(eta(4)-Ph2C(OH)CH=C-2,6-(PPh2CH2)(2)C6H3), respectively. Dehydration was observed in the coupling reactions of RuCl(PPh3)(PCP) with HC equivalent to CC(OH)PhMe and HC equivalent to C-cyclo-C6H10(OH). Thus, the coupling products RuCl(PPh3)(eta(4)-CH2=CPhCH=C-2,6-(PPh2-CH2)(2)C6H3) and RuCl(PPh3)(eta(4)-cyclo-C6H9-CH=C-2,6-(PPh2CH2)(2)C6H3) were obtained from the reactions of RuCl(PPh3)(PCP) with HC equivalent to CC(OH)PhMe and HC equivalent to C-cycle-C6H10(OH), respectively. Treatment of [Ru(PMe3)(2)(PCP)]BF4 with PhC equivalent to CH produced [Ru(PMe3)(2)(eta(4)-PhCH=C-2,6-(PPh2CH2)(2)C6H3)]BF4.

  DOI：

  10.1021/om9700829