[Cu((dipp)N(H)(C(Me)2)2C(Me)O)2(OTf)2] | 1239315-30-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu((dipp)N(H)(C(Me)2)2C(Me)O)2(OTf)2]
• 英文别名: [copper(II)((2,6-diisopropylphenyl)N(H)(C(Me))2C(Me)O)2(trifluoromethanesulfonate)2]
• CAS: 1239315-30-0
• 化学式: C₃₈H₅₄CuF₆N₂O₈S₂
• 分子量: 908.524
• InChiKey: PXUPCBZUMGIFAI-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  4-(2,6-diisopropylphenyl)amino-3-methylpent-3-en-2-one 、 copper(II) bis(trifluoromethanesulfonate) 以 四氢呋喃 为溶剂， 以93%的产率得到[Cu((dipp)N(H)(C(Me)2)2C(Me)O)2(OTf)2]
  参考文献：
  名称：

  Ketiminato and ketimine Co, Eu, Cu and Fe complexes

  摘要：

  A series of metal complexes have been prepared using two similar ketiminato ligands, (ArLH)-H-1 (([RN(H)(C(Me))(2)C(Me)= O], ((R = 2,6-diisopropylphenyl (Dipp) or 2,6-dimethylphenyl, (Dmp)) and the less bulky, multidentate molecule (LH)-H-2, ([RN(H)C(Me)CHC(Me)= O] (R = C2H4NEt2)). Reaction of (ArLH)-H-1 or (ArLNa)-Na-1 with Co(SCN)(2), Eu(OTf)(3) and Cu(OTf)(2), afforded [Co(DippL(1)H)(2)(NCS)(2)] (1), [Eu(DippL(1)H)(3)(OTf)(3)] (2), and [Cu(OTf)(2)(DippL(1)H)(2)] (3). The coordination preferences of ArL1 and L-2 with FeBr2 were investigated and yielded crystals of [Fe(DippL(1))(2)] (4), [(LFeBr)-Fe-2 center dot LiBr(THF)(2)] (5), and [{(DmpN = C(Me))(2)C(H)Me}FeBr2] (6). Complexes 1-6 have been structurally characterized by X-ray crystallography, and other pertinent techniques. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.019