[Cu(abt)] | 1238336-93-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(abt)]
• 英文别名: [copper(I)(μ3-2-aminobenzenethiol(-H)]；2-aminobenzenethiolate;copper(1+)
• CAS: 1238336-93-0
• 化学式: C₆H₆NS*Cu
• 分子量: 187.732
• InChiKey: UASWYKSZUPSTMI-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  copper(l) iodide 、 2-氨基苯硫醇 在 triethylamine 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以43%的产率得到[Cu(abt)]
  参考文献：
  名称：

  A metallopolymer, [Cu(abt)]∞ (abt, 2-aminobenzenethiol) with novel structural patterns resembling black phosphorus

  摘要：

  A copper(I) complex of 2-aminobenzenethiol, [Cu(abt)](infinity) (1), has been synthesized and characterized. The crystal structure determination indicates a two-dimensional metallopolymeric network formed by edge and corner sharing [Cu(mu(3)-S)N] coordination tetrahedra wherein the copper(I) centers are coordinated to three bridging thiolate donors and the amino group of 2-aminobenzenethiolate. The copper, the sulfur and the nitrogen atoms form sub-lattices that reveal independently striking similarities to the doublelayers present in black phosphorus. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.03.008