| 1374430-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1374430-42-8
• 化学式: C₃₉H₃₄AuF₆N₂P
• 分子量: 872.643
• InChiKey: KNJIJGOONXKRBV-JMXCYVNDSA-N

反应信息

• 作为产物：
  描述：

  三苯基膦氯金 、 以 四氢呋喃 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Structural variation in gold(I)-chelate systems: Synthesis of an asymmetrically bridged β-diketiminato complex of gold

  摘要：

  The reaction of the potassium diketiminate K[RN=C(CF3)CH=(CF3)CNR)], where R = 3,5-C6H3Me2, with PPh3AuCI afford the complex [RN=C(CF3)CH=(CF3)CNR)AuPPh3]. Unlike gold(I) diketiminates without backbone-CF3 substituents, the complex is thermally stable in the solid state and in solution. The crystal structure confirms that, unlike previous examples of Au(I) ketiminates, this complex possesses a threecoordinate metal centre with a distorted Y-shaped coordination geometry. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.02.026