tris(styrene-1,2-dithiolato)molybdenum | 110348-79-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(styrene-1,2-dithiolato)molybdenum
• 英文别名: [Mo(sdt)3]
• CAS: 110348-79-3
• 化学式: C₂₄H₁₈MoS₆
• 分子量: 594.743
• InChiKey: XZVSCXKHPGOXIY-WRAAWFJZSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  10.14
• 重原子数：
  31.0
• 可旋转键数：
  3.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  bis(acetylacetonato)dioxidomolybdenum(VI) 、 2-(NN-diethylamino)-4-phenyl-1,3-dithiolium hydrogen sulphate 在 盐酸 、 sodium hydroxide 作用下， 以 甲醇 为溶剂， 以10-20的产率得到tris(styrene-1,2-dithiolato)molybdenum
  参考文献：
  名称：

  不对称取代的二硫代戊二烯过渡金属配合物的新合成路线：金属二硫代戊二烯环电流的证据

  摘要：

  2 - N，N-二乙氨基-4-苯基-1,3-二硫鎓硫酸氢盐{[ NEt 2 ] [HSO 4 ]}的碱解在金属络合物的存在下已被用于制备[M {S（Ph）C C（H）S} 3 ] n –（M = Mo，W; n = O：M = V，n = 1）络合物；这些系统的1 H nmr研究表明，金属二硫代噻吩环维持抗磁环电流。

  DOI：

  10.1039/c39870000800

文献信息

• Molybdenum(<scp>vi</scp>) tris(dithiolene) complexes as a new class of three-dimensional two-photon absorption chromophores at telecommunications wavelengths
  作者：Li Qu、Nikolay S. Makarov、Cheng Zhong、Joseph W. Perry、Jingui Qin

  DOI：10.1039/c3tc31058b

  日期：——

  Two molybdenum(VI) tris(dithiolene) complexes with phenyl or naphthyl substituents were synthesized and their two-photon absorption properties were investigated by an open-aperture Z-scan technique using near-infrared femtosecond laser pulses. Both of these complexes exhibited significant two-photon cross sections around the wavelength of 1.3 μm, with the naphthyl substituted complex showing a two-photon cross section of 660 × 10−50 cm4 s−1 photon−1, suggesting a new class of three-dimensional chromophore for use at telecommunications wavelengths.

  研究人员合成了两种具有苯基或萘基取代基的三(二硫环戊烯)钼(VI)配合物，并利用近红外飞秒激光脉冲，通过开孔 Z 扫描技术研究了它们的双光子吸收特性。这两种复合物都在 1.3 μm 波长附近表现出显著的双光子截面，其中萘基取代的复合物表现出 660 × 10-50 cm4 s-1 光子-1 的双光子截面，这表明有一类新的三维发色团可用于电信波长。
• Synthesis, Cyclic Voltammetric and Electrospray Mass Spectrometric Studies of a Series of Tris-Substituted 1,2-Dithiolene Complexes of Tungsten and Molybdenum
  作者：Polycarpos Falaras、Christine-Anne Mitsopoulou、Dimitris Argyropoulos、Emmanuel Lyris、Nikos Psaroudakis、Ersi Vrachnou、Dimitris Katakis

  DOI：10.1021/ic00122a008

  日期：1995.8

  Ten new nonsymmetric dithiolenes of the general formula [RR'(C2S2)](3)M were synthesized, from the corresponding 1,3-dithiol-2-ones, or from the corresponding mixed benzoins and tetraphosphorus decasulfide. The redox properties of these ten complexes together with those of the symmetric ones with R = R' = Ph and M = Mo or W, were investigated by cyclic voltammetry. Two processes were only observed, assigned to C --> C1- and C1- --> C2- (C the complex), for which the quasi-reversible E(1/2) potentials are highly dependent on the nature of the central metal ion, and for the same metal on the nature of the ligand and on the substituents on the phenyl rings. The ease by which the complexes are reduced is most likely the reason they give ESMS (negative mode) spectra, in spite of the fact they are neutral in solution. The process of this reduction and the parameters affecting it are investigated and discussed.