N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediamine | 807613-88-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediamine
• 英文别名: 4-[[4,5-Dichloro-2-[(2,4-dihydroxyphenyl)methylideneamino]phenyl]iminomethyl]benzene-1,3-diol
• CAS: 807613-88-3
• 化学式: C₂₀H₁₄Cl₂N₂O₄
• 分子量: 417.248
• InChiKey: WTJQFPMGTUOQNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediamine 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 Ni(II)[N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediaminato]disodium salt
  参考文献：
  名称：

  Self-assembled monolayers of bis(salicylaldiminato)nickel(II) Schiff-base complexes: synthesis and structure

  摘要：

  The synthesis of two derivatized Ni-II Schiff-base complexes is reported. Self-assembled monolayers (SAMs) have been obtained by reaction of coupling layers, functionalized glass substrates and the derivatized complex precursors. The self-assembled films have been characterized by contact angle measurements, X-ray photoelectron spectroscopy, and UV-Vis absorption spectroscopy. A structure of these SAMs is proposed on the basis of spectroscopic data and molecular metrical parameters. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.04.011