2,5-bis[(4-chlorocarboxyanilino)carbonyl]pyridine | 1227367-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5-bis[(4-chlorocarboxyanilino)carbonyl]pyridine
• CAS: 1227367-71-6
• 化学式: C₂₁H₁₃Cl₂N₃O₄
• 分子量: 442.258
• InChiKey: KVXQURGQHRSDBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.34
• 重原子数：
  30.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105.23
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  2,5-bis[(4-carboxyanilino)carbonyl]pyridine 在 吡啶 、 氯化亚砜 作用下， 生成 2,5-bis[(4-chlorocarboxyanilino)carbonyl]pyridine
  参考文献：
  名称：

  Synthesis and characterization of new polyesters based on 2,5-bis[(4-chloro carboxyanilino) carbonyl] pyridine and aromatic diols

  摘要：

  Six new polyesters 7a-f were synthesized through the solution polycondensation reaction of diacid chloride 5 with six aromatic diols 6a-f in NN-dimethyl acetamide (DMAc) as solvent in the presence of pyridine as base. The polycondensation reaction produced a series of novel polyester containing pyridyl moiety in the main chain in high yields with inherent viscosities between 0.35 and 0.54 dL/g. The resulted polymers were fully characterized by means of FT-IR spectroscopy, elemental analyses, inherent viscosity and solubility tests. Thermal properties of these polymers were investigated by using thermal gravimetric analysis (TGA) and differentional thermal gravimetric (DTG). The glass-transition temperatures of these polyesters were recorded between 130 and 170 degrees C by differential scanning calorimetry (DSC) and the 10% weight loss temperatures were ranging from 390 to 450 degrees C under nitrogen. (C) 2009 Khalil Faghihi. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2009.08.002