2-methylthioxanthene sulfoxide | 135566-33-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻喃类
• 英文名称: 2-methylthioxanthene sulfoxide
• 英文别名: 2-methyl-9H-thioxanthene 10-oxide
• CAS: 135566-33-5
• 化学式: C₁₄H₁₂OS
• 分子量: 228.315
• InChiKey: IKYDHTNTDUVNMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基-9H-噻吨-9-酮 在 硼烷 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 1.5h， 生成 2-methylthioxanthene sulfoxide
  参考文献：
  名称：

  Mlotkowska, B. L.; Cushman, James A.; Harwood, J., Journal of Heterocyclic Chemistry, 1991, vol. 28, # 3, p. 731 - 736

  摘要：

  DOI：

文献信息

• Preparation of low loss optical material from difunctional silyl enol ethers and difunctional silanols
  申请人：——

  公开号：US20030232951A1

  公开（公告）日：2003-12-18

  Certain compounds within the general formula (I) 1 wherein: Ra and Ra′ are independently alkyl, aryl or aralkyl; Rb and Rb′ are independently CH 2 , CH-alkyl, CH-aryl or CH-aralkyl; R 1 and R 2 , are independently selected from substituted or unsubstituted alkyl, aryl, aralkyl, heteroaryl, heteroaralkyl; and m is at least 1, and preferably fluorinated or cross-linkable under controlled conditions. Compounds of formula (I) are reactable with silanediols to produce linear polycondensate organosiloxanes of defined structure without uncontrolled crosslinking. The polycondensates may be cured and are suitable as optical materials.

  在通用公式(I)1中，某些化合物如下：其中：Ra和Ra′独立地为烷基、芳基或芳烷基；Rb和Rb′独立地为CH2、CH-烷基、CH-芳基或CH-芳烷基；R1和R2独立地选自取代或不取代的烷基、芳基、芳烷基、杂芳基、杂芳烷基；m至少为1，最好是氟化的或在控制条件下可交联的。公式(I)的化合物可以与硅二醇反应，产生具有明确定义结构的线性多聚缩合有机硅氧烷，而不会发生不受控制的交联。这些多聚缩合物可以固化，并适合用作光学材料。
• IONIC COMPOUND, COMPOSITION, CURED MATERIAL, HYDROGEL AND OPHTHALMIC LENS
  申请人：Satake Kohsuke

  公开号：US20130202551A1

  公开（公告）日：2013-08-08

  An ionic compound capable of providing a cured material having superior antibacterial property and oxygen permeability, and a composition containing the ionic compound, and a cured material, a hydro gel and an ophthalmic lens which have long-term sustainable antibacterial property and superior oxygen permeability. The ionic compound is represented by the following formula (1): In formula (1), P represents a polymerizable functional group. Q + represents a cationic group: Z represents an n-valent siloxanyl group in which the total atomic weight of a group of constituent atoms is no less than 70 and no greater than 1,000; X m− represents an m-valent anion; and n is an integer of 1 to 10, where provided that n is no less than 2, a plurality of P3 and Q + 3 are each independently as defined above.

  一种离子化合物，能够提供具有优越抗菌性能和氧透性的固化材料，以及含有该离子化合物的组合物，以及具有长期可持续抗菌性能和优越氧透性的固化材料、水凝胶和眼镜片。该离子化合物由以下式（1）表示： 在式（1）中，P代表可聚合的功能基团。Q + 代表阳离子基团：Z代表一个n价硅氧烷基团，其中构成原子的总原子量不小于70且不大于1,000；X m− 代表m价阴离子；n为1至10的整数，其中n不小于2时，多个P3和Q + 3分别独立定义如上所述。
• Novel Compound, Photosensitive Resin Composition Comprising the Same, and Color Filter
  申请人：Samsung SDI Co., Ltd.

  公开号：US20170107224A1

  公开（公告）日：2017-04-20

  A compound represented by Chemical Formula 1 wherein each substituent is the same as defined in the specification, a photosensitive resin composition including the same, and a color filter manufactured using the photosensitive resin composition are provided.

  提供了一种由化学式1表示的化合物，其中每个取代基与规范中定义的相同，包括该化合物的感光树脂组合物，以及使用该感光树脂组合物制造的彩色滤光片。
• COMPOSITION CONTAINING VINYL-GROUP-CONTAINING COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160046552A1

  公开（公告）日：2016-02-18

  A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

  这个组合物包含一种含有新颖乙烯基团的化合物。该组合物包含一个由通式（1）表示的含有乙烯基团的化合物。在该式中：W1和W2代表由通式（2）表示的一个基团（其中环（Z）是芳香烃环，X是一个单键或—S—，R1是一个单键或C1-4烷基基团，R2是特定的取代基团，如一价碳氢化合物，m是大于或等于0的整数），一个由通式（4）表示的基团（其中环（Z）、X、R1、R2和m如前述），一个羟基，或一个（甲基）丙烯酰氧基团；环（Y1、Y2）是芳香烃环；R代表一个单键或一个特定的二价基团；R3a和R3b代表氰基、卤素原子或一价碳氢基团；n1和n2是0-4的整数。
• PHOTOBASE GENERATOR
  申请人：SAN-APRO LTD.

  公开号：US20160009737A1

  公开（公告）日：2016-01-14

  There is provided a photobase generator and a photosensitive resin composition containing the photobase generator. The photobase generator includes an ammonium salt represented by general formula (1). In formula (1), R 1 to R 4 independently represent an alkyl group having 1 to 18 carbon atoms or Ar, wherein at least one of R 1 to R 4 represents Ar; Ar represents an aryl group having 6 to 14 carbon atoms (excluding carbon atoms contained in a substituent as mentioned below), wherein some of hydrogen atoms in the aryl group may be independently substituted by an alkyl group having 1 to 18 carbon atoms or the like; Y + represents an ammonio group represented by general formula (2) or (3); and E represents a hydrogen atom or a group represented by general formula (5).

  提供了一种光碱基发生剂和含有该光碱基发生剂的光敏树脂组合物。光碱基发生剂包括由通式（1）表示的铵盐。在通式（1）中，R1至R4分别代表具有1至18个碳原子的烷基基团或Ar，其中至少有一个R1至R4代表Ar；Ar代表具有6至14个碳原子的芳基团（不包括下文所述取代基中的碳原子），芳基团中的一些氢原子可以独立地被具有1至18个碳原子的烷基基团或类似物所取代；Y+表示由通式（2）或（3）表示的铵基团；E表示氢原子或由通式（5）表示的基团。